Month: October 2021

In 2019 TOXICOL IN VITRO published article about BOVINE CORNEAL OPACITY; TIME EXPOSURE TEST; HPLC/UPLC-SPECTROPHOTOMETRY; HAZARD IDENTIFICATION; APPLICABILITY DOMAIN; CHEMICALS; ASSAY; VALIDATION in [Alepee, N.] LOreal Res & Innovat, Aulnay Sous Bois, France; [Adriaens, E.] Adriaens Consulting, Aalter, Belgium; [Abo, T.] Kao Corp, Safety Sci Res, Kawasaki, Kanagawa, Japan; [Bagley, D.] Colgate Palmolive Co, Piscataway, NJ USA; [Desprez, B.] Cosmet Europe Personal Care Assoc, Brussels, Belgium; [Hibatallah, J.] Chanel Parfums Beaute, Neuilly Sur Seine, France; [Mewes, K.] Henkel AG & Co KGaA, Dusseldorf, Germany; [Pfannenbecker, U.] Beiersdorf AG, Hamburg, Germany; [Sala, A.] Kao Corp SA, Barcelona, Spain; [Sala, A.] HP Inc, Barcelona, Spain; [Van Rompay, A. R.; Verstraelen, S.] VITO NV Flemish Inst Technol Res, Mol, Belgium; [McNamee, P.] Procter & Gamble Co, Egham, Surrey, England in 2019, Cited 36. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4. Application In Synthesis of 5-Norbornene-2-carbonitrile

The focus of Cosmetics Europe’s programme on serious eye damage/eye irritation is on development of testing strategies and defined approaches for identification of ocular effects of chemicals in the context of OECD’s Guidance Document on an Integrated Approach on Testing and Assessment (IATA) for Serious Eye Damage and Eye Irritation. Cosmetics Europe created a comprehensive database of chemicals for which in vitro data are available with corresponding historical in vivo Draize eye data. This database allowed further exploration of the initially proposed strategies from the CON4EI project and to identify opportunities for refinement. The current analysis focused on the development of a defined approach, applicable to liquid non-surfactant chemicals, neat and in dilution, that can distinguish between the three UN GHS categories (Cat. 1, Cat. 2, and No Cat.). Combining the modified-protocol Short Time Exposure (STE) test method (OECD TG 491 with extension to highly volatile substances) with the Bovine Corneal Opacity and Permeability Laser Light-Based Opacitometer (BCOP LLBO) test method in a Bottom-Up approach identified 81.2% Cat. 1, 56.3% Cat. 2, and 85.3% No. Cat correctly, with an NPV of 96.7% and a PPV of 68.6%. Therefore, the performance of the defined approach was better than the standalone test methods.

Application In Synthesis of 5-Norbornene-2-carbonitrile. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Alepee, N; Adriaens, E; Abo, T; Bagley, D; Desprez, B; Hibatallah, J; Mewes, K; Pfannenbecker, U; Sala, A; Van Rompay, AR; Verstraelen, S; McNamee, P or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Computed Properties of C8H9N. Authors Bar-Or, RL; Kor, A; Jaljuli, I; Lev-Ran, S in KARGER published article about in [Bar-Or, Ruth Lev; Kor, Ariel; Lev-Ran, Shaul] Israel Ctr Addict ICA, Hazoran St 2, IL-4250602 Netanya, Israel; [Bar-Or, Ruth Lev] Hebrew Univ Jerusalem, Hadassah Sch Publ Hlth & Community Med, Jerusalem, Israel; [Kor, Ariel] Interdisciplinary Ctr IDC, Herzliyya, Israel; [Kor, Ariel] Yale Univ, Yale Sch Med, New Haven, CT USA; [Jaljuli, Iman] Tel Aviv Univ, Dept Stat & Operat Res, Tel Aviv, Israel; [Lev-Ran, Shaul] Lev Hasharon Med Ctr, Netanya, Israel; [Lev-Ran, Shaul] Tel Aviv Univ, Dept Psychiat, Sackler Fac Med, Tel Aviv, Israel in , Cited 51. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4

Introduction: Substance use disorders (SUDs) are a leading cause of morbidity and mortality worldwide, having a profound and global impact on health, well-being, safety, and productivity. Although traditionally the prevalence of SUDs in Israel has been estimated to be lower than those in high-income countries, estimates and characteristics of individuals with SUDs in the past decade are lacking. In this work, we explored the prevalence of SUDs among the adult Jewish population in Israel, per different classes of substances across sex, age group, and other sociodemographic factors. Methods: Data from an online representative sample of 4,025 respondents were collected, including the alcohol, smoking, and substance involvement screening test (ASSIST) metric and sociodemographic data. Results: We found that the most common SUDs were alcohol (10.5% [9.5-11.4]), cannabis (9.0% [8.2-9.9]), and sedative (3.6% [3.0-4.2]) use disorders. Alcohol-cannabis (3.2% [2.7-3.7]) and alcohol-sedative (1.04% [0.7-1.35]) were the most prevalent co-occurring SUDs. Among those with cannabis use disorder, the prevalence of alcohol use disorder was found to be 35.3% [30.4-40.2]. The estimated risk for alcohol use disorder was found to be inversely proportional to age, cannabis use disorder increased, peaked, and decreased with age, and that of sedative use disorder increased with age, particularly among women. While older individuals (in the 51-60 years of age group) were at lower risk (OR = 0.5 [0.3, 0.8]) compared to those <20 years of age for alcohol use disorder, they were at increased risk for sedative use disorder (OR = 3.1 [1.2, 9.7]). Conclusions: These findings represent substantially higher rates of SUDs in Israel than those previously reported and should affect resources allocated to addiction prevention and treatment. Further research on the role of gender, age, culture, and ethnicity in the propensity to develop SUDs is necessary for the development of more focused preventive and intervention measures. Focusing on non-Jewish populations in Israel and broadening the scope to include behavioral addictions should be addressed in future studies. Computed Properties of C8H9N. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Bar-Or, RL; Kor, A; Jaljuli, I; Lev-Ran, S or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

An article Polysiloxane assisted fabrication of chiral crystal sponge coated capillary column for chiral gas chromatographic separation WOS:000503319300020 published article about METAL-ORGANIC FRAMEWORKS; ABSOLUTE STRUCTURE DETERMINATION; STATIONARY PHASES; ENANTIOMER SEPARATION; RESOLUTION; RECOGNITION; HPLC; SULFOXIDES; CATALYSIS; ISOMERS in [Wang, Zi-Meng; Yang, Cheng-Xiong] Nankai Univ, Tianjin Key Lab Mol Recognit & Biosensing, Res Ctr Analyt Sci, Coll Chem, Tianjin 300071, Peoples R China; [Yan, Xiu-Ping] Jiangnan Univ, State Key Lab Food Sci & Technol, Int Joint Lab Food Safety, Inst Analyt Food Safety,Sch Food Sci & Technol, Wuxi 214122, Jiangsu, Peoples R China in 2019, Cited 51. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4. Formula: C8H9N

Chiral crystalline sponges (CCSs) are a recent class of chiral porous metal complexes potential in chiral recognition. Here we report the fabrication of polysiloxane OV-1701 incorporated CCS-3S (PSO/CCS-3S) coated capillary column as a novel stationary phase for gas chromatographic separation of diverse race-mates. CCS-3S with the chiral ligand of (S)-mandelic was selected as the model CCS. With the aid of polysiloxane OV-1701, PSO/CCS-3S coated capillary column gave improved resolution, broader enantiomers separation scope and much larger McReynolds constants than CCS-3S coated capillary column. Many racemates that cannot be separated on CCS-3S coated capillary column were well resolved on PSO/CCS-3S coated capillary column. The PSO/CCS-3S coated capillary column also gave wide linear range, low limit of detection, good repeatability and reproducibility, and fine inertness and anti-column bleeding properties for the separation of enantiomers. In addition, the PSO/CCS-3S coated capillary column presented better resolution for the studied racemates than commercial beta-cyclodextrin based Cyclosil B (30 m long x0.32 mm i.d. x 0.25 mu m film thickness), beta-DEX 225 (30 m long x0.25 mm i.d. x 0.25 mu m film thickness) and amino acid based Chirasil L-Val (25 m long x0.25 mm i.d. x 0.12 mu m film thickness) capillary columns. These results indicate the great potential of PSO/CCS-3S coated capillary column in separation of enantiomers. (C) 2019 Elsevier B.V. All rights reserved.

Formula: C8H9N. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Wang, ZM; Yang, CX; Yan, XP or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

I found the field of Dentistry, Oral Surgery & Medicine; Surgery very interesting. Saw the article Management of anaemia and blood in patients having neck dissections or free flaps for head and neck cancer published in 2019. Recommanded Product: 95-11-4, Reprint Addresses Rogers, SN (corresponding author), Aintree Univ Hosp NHS Fdn Trust, Reg Maxillofacial Unit, Liverpool L9 1AE, Merseyside, England.. The CAS is 95-11-4. Through research, I have a further understanding and discovery of 5-Norbornene-2-carbonitrile

Our main aims were to assess haemoglobin (Hb) concentrations from preoperative assessment to discharge from hospital, and to review which patients had blood transfusions and compliance with national transfusion guidelines. We studied a consecutive series of 131 patients between October 2016 and September 2017 who had either neck dissection or resection and free microvascular tissue transfer. Half the patients had soft tissue free flaps (n=65), 26% had composite free flaps (n = 34), and 24% neck dissection only (n =32). Using the WHO definition of anaemia, 4% (1/28) of patients who had neck dissections and 19% (16/85) of those who had free flaps were anaemic preoperatively. The median (IQR) Hb at discharge was 131 (119-144) g/L for patients who had neck dissections, 103 (95-114) g/L for those who had soft free flaps, and 95 (90-104) g/L for those who had composite free flaps. No patients who had neck dissection were given a red blood cell (RBC) transfusion, whereas they were given to 26/99 (26%) of those who had free flaps. Hb concentrations were checked after each unit in 31/39 transfusions (79%). Concentrations for those who had free flaps fell by about 30 g/L from admission to operation, and only four patients were given tranexamic acid peroperatively. Postoperatively Hb remained at similar concentrations until discharge, with 23/98 (24%) given iron orally on discharge. In terms of compliance with blood transfusion guidelines there was a notable absence of the use of tranexamic acid and of iron intravenously. An increase in their use could potentially reduce the number of blood transfusions required and the postoperative incidence of anaemia, and have a favourable effect on outcomes such as complications, fatigue, and overall quality of life. (C) 2019 The British Association of Oral and Maxillofacial Surgeons. Published by Elsevier Ltd. All rights reserved.

Recommanded Product: 95-11-4. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Rogers, SN; Horisk, K; Groom, P; Lowe, D or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Biomolecule-derived supported cobalt nanoparticles for hydrogenation of industrial olefins, natural oils and more in water published in 2019. Recommanded Product: 95-11-4, Reprint Addresses Beller, M (corresponding author), Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany.. The CAS is 95-11-4. Through research, I have a further understanding and discovery of 5-Norbornene-2-carbonitrile

Catalytic hydrogenation of olefins using noble metal catalysts or pyrophoric RANEY (R) nickel is of high importance in the chemical industry. From the point of view of green and sustainable chemistry, design and development of Earth-abundant, less toxic, and more environmentally friendly catalysts are highly desirable. Herein, we report the convenient preparation of active cobalt catalysts and their application in hydrogenations of a wide range of terminal and internal carbon-carbon double bonds in water under mild conditions. Catalysts are prepared on multi-gram scale by pyrolysis of cobalt acetate and uracil, guanine, adenine or l-tryptophan. The most active material Co-Ura/C-600 showed good productivity in industrially relevant hydrogenation of diisobutene to isooctane and in natural oil hardening.

Recommanded Product: 95-11-4. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Pews-Davtyan, A; Scharnagl, FK; Hertrich, MF; Kreyenschulte, C; Bartling, S; Lund, H; Jackstell, R; Beller, M or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Alnaimat, AS; Barciela-Alonso, MC; Herbello-Hermelo, P; Dominguez-Gonzalez, R; Bermejo-Barrera, P in [Alnaimat, Ala S.; Carmen Barciela-Alonso, Maria; Herbello-Hermelo, Paloma; Dominguez-Gonzalez, Raquel; Bermejo-Barrera, Pilar] Univ Santiago de Compostela, Dept Analyt Chem Nutr & Bromatol, Fac Chem, Grp Trace Elements Speciat & Spect GETEE,Strateg, Ave Ciencias S-N, Santiago De Compostela 15782, Spain; [Alnaimat, Ala S.] Al Hussein Bin Talal Univ, Coll Sci, Dept Chem, Maan, Jordan published In vitro assessment of major and trace element bioaccessibility in tea samples in 2021, Cited 46. Formula: C8H9N. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4.

Bioaccessibility of trace elements (Li, Be, Ti, Ga, Cu, Ag, Hg, Cd, Cs, Pt, Tl, Pb, As, Cr, Co, Ni, V, Se, Sn and Sb) and major elements (Rb, Ba, Al, Fe, Zn, Si, Ca, Mg, Mn, Mo, Sr, P and K) in tea infusions has been assessed using an in vitro dialyzability protocol. Gastric simulation (using pepsin solution) and intestinal simulation (using pancreatin and bile salts) were used to perform the in vitro digestion. ICP-MS, ICP-OES and FAES were used for elements determination in digested tea leaves, their infusions and the dialyzate fractions from tea infusions. Microwaves assisted acid digestion was used for the total element determination in tea leaves, while tea infusions were prepared by brewing tea leaves for 5 min in boiling water. The LODs for elements determined in tea leaves were in the range of 0.11-656 ng g(-1) and 0.02-145.6 mu g g(-1) for trace and major elements, respectively. For elements’ determination in tea infusions, the LODs were ranged between 0.23 and 399.9 ng L-1 for trace elements and 0.2-1248 mu g L-1 for major elements. The LODs for the elements in the dialyzable fraction varied from 0.018 to 142 mu g L-1. The accuracy of the total element determination was evaluated using certified reference materials (Tea Leaves INCT-TL-1 and Rye Grass). The analytical recoveries were also assessed for analyzed elements in digested tea leaves (95-114%) and their infusions (92-115%), showing good recoveries. Among the studied elements, K was the most abundant element in tea leaves and tea infusions in almost all samples, followed by Ca, Mg, and P. Zn, Cs, and K showed the highest dialyzability percentages up to 84%, 76%, and 54%, respectively, followed by Si and Ca and K that show moderate to high dialyzability percentages. The accuracy of the dialysis process was evaluated using a mass-balance study.

Formula: C8H9N. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Alnaimat, AS; Barciela-Alonso, MC; Herbello-Hermelo, P; Dominguez-Gonzalez, R; Bermejo-Barrera, P or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Recently I am researching about LIQUID-PHASE HYDROGENATION; HIGHLY-ACTIVE HYDROGENATION; ORGANIC FRAMEWORK NODES; ASYMMETRIC HYDROGENATION; SELECTIVE HYDROGENATION; CATALYTIC-HYDROGENATION; COMPLEXES; ISOOCTENES; KINETICS; CO, Saw an article supported by the State of Mecklenburg Western Pomerania, the BMBFFederal Ministry of Education & Research (BMBF) [03XP0060]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Pews-Davtyan, A; Scharnagl, FK; Hertrich, MF; Kreyenschulte, C; Bartling, S; Lund, H; Jackstell, R; Beller, M. The CAS is 95-11-4. Through research, I have a further understanding and discovery of 5-Norbornene-2-carbonitrile. Application In Synthesis of 5-Norbornene-2-carbonitrile

Catalytic hydrogenation of olefins using noble metal catalysts or pyrophoric RANEY (R) nickel is of high importance in the chemical industry. From the point of view of green and sustainable chemistry, design and development of Earth-abundant, less toxic, and more environmentally friendly catalysts are highly desirable. Herein, we report the convenient preparation of active cobalt catalysts and their application in hydrogenations of a wide range of terminal and internal carbon-carbon double bonds in water under mild conditions. Catalysts are prepared on multi-gram scale by pyrolysis of cobalt acetate and uracil, guanine, adenine or l-tryptophan. The most active material Co-Ura/C-600 showed good productivity in industrially relevant hydrogenation of diisobutene to isooctane and in natural oil hardening.

About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Pews-Davtyan, A; Scharnagl, FK; Hertrich, MF; Kreyenschulte, C; Bartling, S; Lund, H; Jackstell, R; Beller, M or concate me.. Formula: C8H9N

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

An article In vitro assessment of major and trace element bioaccessibility in tea samples WOS:000652032600119 published article about CAMELLIA-SINENSIS L.; BLACK TEAS; ICP-MS; BIOAVAILABILITY; INFUSIONS; CALCIUM; METALS; FE; CLASSIFICATION; CONTAMINATION in [Alnaimat, Ala S.; Carmen Barciela-Alonso, Maria; Herbello-Hermelo, Paloma; Dominguez-Gonzalez, Raquel; Bermejo-Barrera, Pilar] Univ Santiago de Compostela, Dept Analyt Chem Nutr & Bromatol, Fac Chem, Grp Trace Elements Speciat & Spect GETEE,Strateg, Ave Ciencias S-N, Santiago De Compostela 15782, Spain; [Alnaimat, Ala S.] Al Hussein Bin Talal Univ, Coll Sci, Dept Chem, Maan, Jordan in 2021, Cited 46. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4. COA of Formula: C8H9N

Bioaccessibility of trace elements (Li, Be, Ti, Ga, Cu, Ag, Hg, Cd, Cs, Pt, Tl, Pb, As, Cr, Co, Ni, V, Se, Sn and Sb) and major elements (Rb, Ba, Al, Fe, Zn, Si, Ca, Mg, Mn, Mo, Sr, P and K) in tea infusions has been assessed using an in vitro dialyzability protocol. Gastric simulation (using pepsin solution) and intestinal simulation (using pancreatin and bile salts) were used to perform the in vitro digestion. ICP-MS, ICP-OES and FAES were used for elements determination in digested tea leaves, their infusions and the dialyzate fractions from tea infusions. Microwaves assisted acid digestion was used for the total element determination in tea leaves, while tea infusions were prepared by brewing tea leaves for 5 min in boiling water. The LODs for elements determined in tea leaves were in the range of 0.11-656 ng g(-1) and 0.02-145.6 mu g g(-1) for trace and major elements, respectively. For elements’ determination in tea infusions, the LODs were ranged between 0.23 and 399.9 ng L-1 for trace elements and 0.2-1248 mu g L-1 for major elements. The LODs for the elements in the dialyzable fraction varied from 0.018 to 142 mu g L-1. The accuracy of the total element determination was evaluated using certified reference materials (Tea Leaves INCT-TL-1 and Rye Grass). The analytical recoveries were also assessed for analyzed elements in digested tea leaves (95-114%) and their infusions (92-115%), showing good recoveries. Among the studied elements, K was the most abundant element in tea leaves and tea infusions in almost all samples, followed by Ca, Mg, and P. Zn, Cs, and K showed the highest dialyzability percentages up to 84%, 76%, and 54%, respectively, followed by Si and Ca and K that show moderate to high dialyzability percentages. The accuracy of the dialysis process was evaluated using a mass-balance study.

COA of Formula: C8H9N. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Alnaimat, AS; Barciela-Alonso, MC; Herbello-Hermelo, P; Dominguez-Gonzalez, R; Bermejo-Barrera, P or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Wang, ZM; Yang, CX; Yan, XP in [Wang, Zi-Meng; Yang, Cheng-Xiong] Nankai Univ, Tianjin Key Lab Mol Recognit & Biosensing, Res Ctr Analyt Sci, Coll Chem, Tianjin 300071, Peoples R China; [Yan, Xiu-Ping] Jiangnan Univ, State Key Lab Food Sci & Technol, Int Joint Lab Food Safety, Inst Analyt Food Safety,Sch Food Sci & Technol, Wuxi 214122, Jiangsu, Peoples R China published Polysiloxane assisted fabrication of chiral crystal sponge coated capillary column for chiral gas chromatographic separation in 2019, Cited 51. SDS of cas: 95-11-4. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4.

Chiral crystalline sponges (CCSs) are a recent class of chiral porous metal complexes potential in chiral recognition. Here we report the fabrication of polysiloxane OV-1701 incorporated CCS-3S (PSO/CCS-3S) coated capillary column as a novel stationary phase for gas chromatographic separation of diverse race-mates. CCS-3S with the chiral ligand of (S)-mandelic was selected as the model CCS. With the aid of polysiloxane OV-1701, PSO/CCS-3S coated capillary column gave improved resolution, broader enantiomers separation scope and much larger McReynolds constants than CCS-3S coated capillary column. Many racemates that cannot be separated on CCS-3S coated capillary column were well resolved on PSO/CCS-3S coated capillary column. The PSO/CCS-3S coated capillary column also gave wide linear range, low limit of detection, good repeatability and reproducibility, and fine inertness and anti-column bleeding properties for the separation of enantiomers. In addition, the PSO/CCS-3S coated capillary column presented better resolution for the studied racemates than commercial beta-cyclodextrin based Cyclosil B (30 m long x0.32 mm i.d. x 0.25 mu m film thickness), beta-DEX 225 (30 m long x0.25 mm i.d. x 0.25 mu m film thickness) and amino acid based Chirasil L-Val (25 m long x0.25 mm i.d. x 0.12 mu m film thickness) capillary columns. These results indicate the great potential of PSO/CCS-3S coated capillary column in separation of enantiomers. (C) 2019 Elsevier B.V. All rights reserved.

SDS of cas: 95-11-4. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Wang, ZM; Yang, CX; Yan, XP or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

An article Polysiloxane assisted fabrication of chiral crystal sponge coated capillary column for chiral gas chromatographic separation WOS:000503319300020 published article about METAL-ORGANIC FRAMEWORKS; ABSOLUTE STRUCTURE DETERMINATION; STATIONARY PHASES; ENANTIOMER SEPARATION; RESOLUTION; RECOGNITION; HPLC; SULFOXIDES; CATALYSIS; ISOMERS in [Wang, Zi-Meng; Yang, Cheng-Xiong] Nankai Univ, Tianjin Key Lab Mol Recognit & Biosensing, Res Ctr Analyt Sci, Coll Chem, Tianjin 300071, Peoples R China; [Yan, Xiu-Ping] Jiangnan Univ, State Key Lab Food Sci & Technol, Int Joint Lab Food Safety, Inst Analyt Food Safety,Sch Food Sci & Technol, Wuxi 214122, Jiangsu, Peoples R China in 2019, Cited 51. Product Details of 95-11-4. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4

Chiral crystalline sponges (CCSs) are a recent class of chiral porous metal complexes potential in chiral recognition. Here we report the fabrication of polysiloxane OV-1701 incorporated CCS-3S (PSO/CCS-3S) coated capillary column as a novel stationary phase for gas chromatographic separation of diverse race-mates. CCS-3S with the chiral ligand of (S)-mandelic was selected as the model CCS. With the aid of polysiloxane OV-1701, PSO/CCS-3S coated capillary column gave improved resolution, broader enantiomers separation scope and much larger McReynolds constants than CCS-3S coated capillary column. Many racemates that cannot be separated on CCS-3S coated capillary column were well resolved on PSO/CCS-3S coated capillary column. The PSO/CCS-3S coated capillary column also gave wide linear range, low limit of detection, good repeatability and reproducibility, and fine inertness and anti-column bleeding properties for the separation of enantiomers. In addition, the PSO/CCS-3S coated capillary column presented better resolution for the studied racemates than commercial beta-cyclodextrin based Cyclosil B (30 m long x0.32 mm i.d. x 0.25 mu m film thickness), beta-DEX 225 (30 m long x0.25 mm i.d. x 0.25 mu m film thickness) and amino acid based Chirasil L-Val (25 m long x0.25 mm i.d. x 0.12 mu m film thickness) capillary columns. These results indicate the great potential of PSO/CCS-3S coated capillary column in separation of enantiomers. (C) 2019 Elsevier B.V. All rights reserved.

Product Details of 95-11-4. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Wang, ZM; Yang, CX; Yan, XP or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts