The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 2,4,5-Triphenylimidazole, is researched, Molecular C21H16N2, CAS is 484-47-9, about New phosphonium molybdate-promoted green, fast and selective catalytic procedure for the synthesis of trisubstituted imidazoles, the main research direction is triaryl imidazole preparation selective green chem; benzil aromatic aldehyde cyclocondensation phosphonium molybdate catalyst; ethane diyl ditriphenylphosphonium hexamolybdate dimethylsulfoxide preparation antibacterial.Quality Control of 2,4,5-Triphenylimidazole.
The compound 1,1′-(ethane-1,2-diyl)ditriphenylphosphonium hexamolybdate dimethylsulfoxide [C2H4[P(C6H5)3]2][Mo6O19].SO(CH3)2 (I) was prepared, and single crystal X-ray diffraction anal. was used to characterize the titled compd (I). Crystallog. data showed that compound (I) crystallized in the monoclinic crystal system in C2/c space group. The compound (I) was used for selective synthesis of 2,4,5-tri aryl imidazole derivatives I (R = Ph, furan-2-yl, 1-naphthyl, etc.) under solvent-free conditions efficiently. Because of hindrance of the catalyst, the yields of products for aldehydes RCHO bearing para substituents are higher than the aldehydes bearing ortho substituents, and for aromatic aldehydes with meta substituents are very low.
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts