《Scope and mechanism of nitrile dihydroboration mediated by a β-diketiminate manganese hydride catalyst》 was written by Nguyen, Thao T.; Kim, Jun-Hyeong; Kim, Suyeon; Oh, Changjin; Flores, Marco; Groy, Thomas L.; Baik, Mu-Hyun; Trovitch, Ryan J.. Recommanded Product: 4-Fluorobenzonitrile And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020. The article conveys some information:
The Manganese hydride dimer, [(2,6-iPr2PhBDI)Mn(μ-H)]2, was found to mediate nitrile dihydroboration, rendering it the 1st Mn catalyst for this transformation. Stoichiometric experiments revealed that benzonitrile insertion affords [(2,6-iPr2PhBDI)Mn(μ-NCHC6H5)]2 en route to N,N-diborylamine formation. D. functional theory calculations reveal the precise mechanism and demonstrate that catalysis is promoted by monomeric species. In the part of experimental materials, we found many familiar compounds, such as 4-Fluorobenzonitrile(cas: 1194-02-1Recommanded Product: 4-Fluorobenzonitrile)
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Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts