Ruske, Walter; Becker, Manfred; Jahns, Hans Joachim published the artcile< Polymerization mechanisms of hydrocyanic acid. II. Reaction of negatively disubstituted acetonitriles with ammonia>, Application In Synthesis of 6136-93-2, the main research area is .
Cl2CHCN and NH3 form 2,4,6-tris(dichloromethyl)-1,3,5-triazine and a black-brown polymer (I). Its infrared spectrum coincides with that of the polymer formed from dichloroacetamidine and NH3 and is very similar to the spectrum of paracyanogen. Elementary analysis of I shows the presence of O, probably introduced by hydrolysis. Polymerization of diethoxyacetonitrile, which has a lesser inductive effect of its C-X dipole than the dichloro compound, does not lead to tris(diethoxymethyl)-1,3,5-triazine. These 2 cases permit a general prediction about the course of the polymerization mechanism of HCN. The reaction has the same selectivity towards the catalyst as the benzoin condensation; the real catalyst is the cyanide ion.
Zeitschrift fuer Chemie published new progress about IR spectra. 6136-93-2 belongs to class nitriles-buliding-blocks, and the molecular formula is C6H11NO2, Application In Synthesis of 6136-93-2.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts