The author of 《Triphenylbismuth Dichloride-Mediated Conversion of Thioamides to Nitriles》 were Gopi, Elumalai; Gravel, Edmond; Doris, Eric. And the article was published in European Journal of Organic Chemistry in 2019. Related Products of 1194-02-1 The author mentioned the following in the article:
Thioamides RC(S)NH2 (R = 4-BrC6H4, Ph, 1-naphthyl, pyridin-4-yl, etc.) were efficiently converted to nitriles RCN using the pentavalent triphenylbismuth dichloride in combination with triethylamine. The reaction involved the dehydrosulfurization of primary thioamides to afford substituted aromatic or aliphatic nitriles in good to excellent yields. The process was also successfully extended to the synthesis of cyanamides R1XCN (R1 = Ph, 2-methoxyphenyl; X = NH, NMe) starting from the corresponding thioureas R1XC(S)NH2 and of thiocyanates R1XCN (R1 = 3-methoxyphenyl; X = S) from dithiocarbamates R1XC(S)NH2. In addition to this study using 4-Fluorobenzonitrile, there are many other studies that have used 4-Fluorobenzonitrile(cas: 1194-02-1Related Products of 1194-02-1) was used in this study.
4-Fluorobenzonitrile(cas: 1194-02-1) is used as chemical intermediate, solvent for perfumes and pharmaceuticals, stabilizer for chlorinated solvents, HPLC analysis, catalyst and component of transition-metal complex catalysts.Related Products of 1194-02-1
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts