The author of 《Impregnated copper ferrite on mesoporous graphitic carbon nitride: An efficient and reusable catalyst for promoting ligand-free click synthesis of diverse 1,2,3-triazoles and tetrazoles》 were Khalili, Dariush; Rezaee, Meysam. And the article was published in Applied Organometallic Chemistry in 2019. Computed Properties of C8H6BrN The author mentioned the following in the article:
Synthesis of magnetic CuFe2O4/g-C3N4 hybrids via a facile method and their catalytic performances were evaluated via click chem. was reported. The structural and morphol. characterization of CuFe2O4, g-C3N4, CuFe2O4/g-C3N4 were carried out by different techniques such as X-ray diffraction, high-resolution transmission electron microscopy, field emission SEM, Fourier IR spectroscopy, vibrating sample magnetometry, thermogravimetric anal. and N2 adsorption-desorption anal. (Brunauer-Emmett-Teller surface area). The utilization of magnetic CuFe2O4/g-C3N4 enabled superior performance in the one-pot azide-alkyne cycloaddition reaction in water using alkyl halides and epoxides as azide precursors without the need of any addnl. agents to afford triazoles I [R = cyclohexyl, allyl, Bn, etc.; Ar = Ph, 2-methoxynaphthalenyl] and II [Ar1 = Ph, 2-methoxynaphthalenyl; R1 = H, Ph, 4-ClC6H4; R2 = H, Et, CH2OPh, etc.]. Also 5-substituted 1H-tetrazoles III [Ar2 = Ph, 4-MeC6H4, 2-ClC6H4, etc.] were prepared via [3 + 2] cycloaddition of sodium azide and aryl nitriles by using magnetic CuFe2O4/g-C3N4 nanoparticles. In addition, the catalytic system highly fulfilled the demands of “”green click chem.”” with its convenient conditions, especially easy access to a variety of significant products in low catalyst loading and simple work-up and isolation procedure.4-Cyanobenzyl bromide(cas: 17201-43-3Computed Properties of C8H6BrN) was used in this study.
4-Cyanobenzyl bromide(cas: 17201-43-3) is an important intermediate for pharmaceutical production. It can be used for the synthesis of a series of piperidine-linked aromatic diimidazolines, which have been synthesized as conformationally restricted congeners of the anti-Pneumocystis carinii (PCP) drug, Pentamidine.Computed Properties of C8H6BrN
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts