《Synthesis of Epoxides from Alkyl Bromides and Alcohols with in Situ Generation of Dimethyl Sulfonium Ylide in DMSO Oxidations》 was published in Journal of Organic Chemistry in 2020. These research results belong to Zhang, Zhi-Wei; Li, Hai-Bo; Li, Jin; Wang, Cui-Cui; Feng, Juan; Yang, Yi-Hua; Liu, Shouxin. Recommanded Product: 17201-43-3 The article mentions the following:
Direct conversion of the readily available alkyl bromides and alcs. to value-added epoxides using DMSO (DMSO) under mild reaction conditions has been developed. Benzyl and allyl bromides, and activated and unactivated alcs. all proceeded smoothly to give epoxides in high to excellent yield. Di-Me sulfide, generated by DMSO oxidations, was in situ elaborated to form the substituted di-Me sulfonium ylide species that participates in the Corey-Chaykovsky epoxidation in a domino and one-pot fashion, resp. After reading the article, we found that the author used 4-Cyanobenzyl bromide(cas: 17201-43-3Recommanded Product: 17201-43-3)
4-Cyanobenzyl bromide(cas: 17201-43-3) is used in the synthesis of ligands containing a chelating pyrazolyl-pyridine group with a pendant aromatic nitrile. It is also useful in the preparation of 4-[(2H-tetra-zol-2-yl)methyl]benzonitrile by reaction with 2H-tetrazole in the presence of potassium hydroxide.Recommanded Product: 17201-43-3
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts