Inorganic compounds containing the −C≡N group are not called nitriles, but cyanides instead.105-34-0, formula is C4H5NO2, Name is Methyl 2-cyanoacetate. Though both nitriles and cyanides can be derived from cyanide salts, most nitriles are not nearly as toxic. Formula: C4H5NO2.
Jucker, Laurent;Aeschi, Yves;Mayor, Marcel research published ã?Aqueous assembly of a (pseudo)rotaxane with a donor-Ï-acceptor axis formed by a Knoevenagel condensationã? the research content is summarized as follows. The incorporation of a linear D-Ï-A “push-pull” chromophore synthesized by a Knoevenagel condensation as axle of a rotaxane was reported. While the introduction of the mech. stoppers by the reversible and thermodynamically controlled Knoevenagel reaction turned out to be challenging, mech. fixation of the superstructure is achieved by “click” chem. in aqueous solution The isolated rotaxane with a red- to NIR-emitting dye as axle displays enhanced emission in aqueous buffered media compared to the unthreaded model chromophore.
Formula: C4H5NO2, Methyl cyanoacetate is an alkyl cyanoacetate ester.
Methyl cyanoacetate is the intermediate product in pharmaceutical organic synthesis as well as in the synthesis of some biologically active compounds used in agriculture. It undergoes calcite or fluorite catalyzed Knövenagel condensation with aromatic aldehydes, giving the corresponding arylidenemalononitriles and (E)-α -cyanocinnamic esters.
Methyl Cyanoacetate is often used as a nucleophile in the electrochemical oxidation of catechols. Methyl Cyanoacetate is also a reagent in the synthesis of Methyl 2-Amino-4-trifluoromethylthiophene-3-carboxylate (M287290); a compound used in the synthesis of DPP-IV inhibitors for treating type 2 diabetes., 105-34-0.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts