Liu, Yingtian; Dang, Xinxin; He, Yu; Bai, Hudong; Chen, Xuehong; Li, Jun-Long; Fan, Junting; Jiang, Hezhong; Li, Jiahong published an article in 2019, the title of the article was Synthesis of 2-cyanoacrylamides through Pd-catalyzed monohydration of methylenemalononitriles.Recommanded Product: 2-(2,3-Dihydro-1H-inden-1-ylidene)malononitrile And the article contains the following content:
A straightforward and efficient method was developed for the synthesis of 2-cyanoacrylamides R1R2C:C(CN)CONH2 [R1 = n-Pr, Ph, 4-MeOC6H4, PhCH:CH, 2-furyl, etc., R2 = H; R1 = Ph, R2 = Me, Ph; R1R2 = (CH2)5, o-C6H4CH2CH2, etc.] from 2-methylenemalononitriles R1R2C:C(CN)2 in good to excellent yields through monohydration under mild and simple reaction conditions. The experimental process involved the reaction of 2-(2,3-Dihydro-1H-inden-1-ylidene)malononitrile(cas: 2510-01-2).Recommanded Product: 2-(2,3-Dihydro-1H-inden-1-ylidene)malononitrile
The Article related to methylene malononitrile preparation diastereoselective monohydration palladium catalyst, cyano acrylamide preparation, Aliphatic Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Recommanded Product: 2-(2,3-Dihydro-1H-inden-1-ylidene)malononitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts