Asai, Kento published the artcilePalladium-Catalyzed Benzylic Silylation of Diarylmethyl Carbonates with Silylboranes under Base-Free Conditions, Safety of Phthalonitrile, the main research area is palladium catalyzed benzylic silylation diarylmethyl carbonate silylborane; benzylic silane nucleophile preparation reaction carbon electrophile.
A palladium-catalyzed benzylic silylation of diarylmethyl carbonates with silylboranes has been developed. The reaction proceeds smoothly even under external base-free conditions, and the corresponding benzylic silanes are formed in good to high yields. The obtained benzyl silane derivatives can work as the benzylic nucleophiles by the action of a suitable fluoride source and react with some carbon electrophiles to deliver the corresponding benzylic C-C cross-coupled products. Addnl., while still preliminary, the allylic silylation of the isoelectronic allylic carbonates is also achieved.
European Journal of Organic Chemistry published new progress about Carbonates Role: RCT (Reactant), RACT (Reactant or Reagent) (diarylmethyl). 91-15-6 belongs to class nitriles-buliding-blocks, name is Phthalonitrile, and the molecular formula is C8H4N2, Safety of Phthalonitrile.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts