Goldberg, Mariano’s team published research in ARKIVOC (Gainesville, FL, United States) in 2021 | CAS: 91-15-6

ARKIVOC (Gainesville, FL, United States) published new progress about Aromatic diamines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 91-15-6 belongs to class nitriles-buliding-blocks, name is Phthalonitrile, and the molecular formula is C8H4N2, Product Details of C8H4N2.

Goldberg, Mariano published the artcileFacile conversion of 1,2-dicyanobenzene into chiral bisamidines, Product Details of C8H4N2, the main research area is chiral bisamidine preparation; diarylethylene diamine dicyanobenzene nucleophilic catalysis acetyl cysteine catalyst.

Nucleophilic catalysis by N-acetyl cysteine permits the smooth reaction of 1,2-diarylethylene-1,2-diamines (R,R)/(S,S)-RCH(NH2)CH(NH2)R (R = Ph, 2-hydroxyphenyl, biphenyl-4-yl, naphth-1-yl, naphth-2-yl) with 1,2-dicyanobenzene forming chiral bisamidines I in yields up to 94% in a single step. Such bisamidines can be used as Bronsted bases or, in the protonated state, as electrophilic catalysts to promote Diels-Alder reactions with medium levels of enantioselectivity.

ARKIVOC (Gainesville, FL, United States) published new progress about Aromatic diamines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 91-15-6 belongs to class nitriles-buliding-blocks, name is Phthalonitrile, and the molecular formula is C8H4N2, Product Details of C8H4N2.

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts