Rodriguez, Jose F. published the artcileSynthesis of 1-Amino-2,2,2-trifluoroalkylphosphonates from Alkene-Tethered Trifluoroacetimidoyl Chlorides, Category: nitriles-buliding-blocks, the main research area is alkene tethered trifluoroacetimidoyl chloride preparation cyclization alkyl phosphite; aminotrifluoroalkyl phosphonate preparation crystal structure; mol structure aminotrifluoroalkyl phosphonate.
The reaction of alkene-tethered trifluoroacetimidoyl chlorides with trialkyl phosphites furnishes 1-amino-2,2,2-trifluoroalkylphosphonates. The products were generated in moderate to good yields, and the scalability of this process was showcased. Partial hydrolysis of the phosphonate moiety was achieved. The cyclization probably occurs via formation of an imidoyl phosphonate intermediate that becomes susceptible to nucleophilic attack at N through the strong electron-withdrawing groups at the imidoyl C.
Organic Letters published new progress about Crystal structure. 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Category: nitriles-buliding-blocks.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts