Xu, Chang published the artcileVisible-Light-Induced α-Amino C-H Bond Arylation Enabled by Electron Donor-Acceptor Complexes, Name: Phthalonitrile, the main research area is tertiary amine benzonitrile photochem regioselective arylation.
Enabled by electron donor-acceptor complexes, a novel visible-light-induced α-amino C-H bond arylation protocol, without a photoredox catalyst, was disclosed. The protocol does not require any transition metal, oxidant, or exclusion of oxygen or moisture. A direct irradiation of the mixture of tertiary amines and benzonitriles with visible light in N,N-diethylethanamide in the presence of Cs2CO3 afforded α-arylated amines in good to excellent yields.
Organic Letters published new progress about Arylation, regioselective. 91-15-6 belongs to class nitriles-buliding-blocks, name is Phthalonitrile, and the molecular formula is C8H4N2, Name: Phthalonitrile.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts