Chen, Zhen-Yu published the artcilePerfluorobutyl Iodide Mediated [1,2] and [2,3] Stevens Rearrangement for the Synthesis of Indolin-3-ones, Formula: C7H6N2, the main research area is indolinone preparation; tertiary aminoaryl ketone Stevens rearrangement perfluorobutyl iodide mediated.
The tertiary amine and ketone components of 1-carbonyl-substituted anilines underwent [1,2] and [2,3] Stevens rearrangement reactions, triggered by a C4F9 radical, formed from electron donor-acceptor complexes. This approach enabled the formation of a quaternary ammonium salt and thus a Stevens rearrangement to afford indolin-3-ones such as I [R1 = Me, Et, i-Pr; R2 = Bn, CH2CH=CH2, C(Me)=C=CH2, etc.; R3 = Me, Bn] and II [R4 = H, Cl, Br; R5 = H, MeO, Cl; R6 = H, MeO] under mild conditions.
Advanced Synthesis & Catalysis published new progress about Indolines Role: SPN (Synthetic Preparation), PREP (Preparation). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Formula: C7H6N2.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts