Ji, Meishan published the artcileCatalyst-free, radical-mediated intermolecular 1,2-arylheteroarylation of alkenes by cleaving inert C-C bond, Synthetic Route of 1885-29-6, the main research area is polyarylalkane preparation photochem; aryldiazonium salt alkene radical tandem arylheteroarylation.
A novel photoinduced intermol. 1,2-arylheteroarylation of alkenes RCH=CH2 (R = t-Bu, Ph, furan-2-yl, etc.) and the efficient synthesis of valuable polyarylalkanes R1-2-MeC(O)C6H3CH2CH(R2)R (R1 = H, 4-Cl, 5-Me, etc.; R2 = pyridin-2-yl, thiazol-2-yl, benzothiazol-2-yl, etc.) are reported. The reaction is operationally simple, proceeds under mild conditions and with no addnl. catalyst and reagents. The strategically designed radical cascade reaction is enabled by electron transfer, and involves cleavage of an inert C-C bond. The process features broad functional group compatibility as well as high product transformability.
Science China: Chemistry published new progress about Alkylarenes Role: SPN (Synthetic Preparation), PREP (Preparation). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Synthetic Route of 1885-29-6.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts