Banerjee, Indrani published the artcileAlkali Metal Catalysed Double Hydrophosphorylation of Nitriles and Alkynes, Category: nitriles-buliding-blocks, the main research area is alkali metal silylamide catalyzed hydrophosphorylation nitrile alkyne; crystal mol structure phosphoryl diphenylphosphinic amide.
Catalytic C-P and N-P bond formation via double hydrophosphorylation of nitriles with diphenylphosphine oxide using alkali metal precatalyst [MN(SiMe3)2] (M = Li, Na, K) is reported. The potassium congener was observed to be the most efficient catalyst for converting aryl nitriles to the corresponding N-((diphenyl-phosphoryl)(aryl)methyl)-P,P-diphenylphosphinic amide [ArCHP(O)-Ph2NHP(O)Ph2] at mild temperature (60°) and with neat reactants. Double hydrophosphorylation of alkynes with HP(O)Ph2 is also very effective when [KN(SiMe3)2] is used as a precatalyst at room temperature and gives the corresponding 1,2-diylbis(diphenyl-phosphine) oxide [RCHP(O)Ph2CH2P(O)Ph2] as the product. A wider substrate scope of both reactions is explored.
European Journal of Inorganic Chemistry published new progress about Alkynes Role: RCT (Reactant), RACT (Reactant or Reagent). 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Category: nitriles-buliding-blocks.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts