Lv, Cong published the artcileFrom amides to urea derivatives or carbamates with chemospecific C-C bond cleavage at room temperature, Safety of 2-Aminobenzonitrile(Flakes or Chunks), the main research area is diaryl acetamide copper catalyst chemoselective bond cleavage; aryl aldehyde preparation; amine pyridinyl diphenylacetamide copper catalyst chemoselective bond cleavage; pyridinyl urea preparation; alc methylpyridinyl diphenylacetamide copper catalyst chemoselective bond cleavage; methylpyridinyl carbamate preparation.
Herein, a significant advancement in this area and present a general method for copper-catalyzed chemospecific C-C bond cleavage of amides to synthesize urea derivatives and carbamates at room temperature was reported. A catalytic process via a resonant six-membered N,O-chelated copper cycle and superoxide radical was proposed according to mechanistic and control experiments The combination of chelation assistance and radical oxygenation strategies opened a door for C-C bond cleavage of common substrates which possess multiple reactive sites and was envision that this broadly applicable method will be of great interest in organic synthesis, the pharmaceutical industry and the agrochem. industry.
Organic Chemistry Frontiers published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Safety of 2-Aminobenzonitrile(Flakes or Chunks).
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts