Nasibipour, Mina published the artcileTuning of the redox potential and catalytic activity of a new Cu(II) complex by o-iminobenzosemiquinone as an electron-reservoir ligand, Application of 2-Aminobenzonitrile(Flakes or Chunks), the main research area is preparation crystal mol structure copper iminobenzosemiquinone complex; EPR spectra magnetic property copper iminobenzosemiquinone complex; cyclic voltammetry copper iminobenzosemiquinone complex; alc oxidation catalyst copper iminobenzosemiquinone complex; homocoupling catalyst copper iminobenzosemiquinone complex.
The synthesis and characterization of a new Cu(II) complex, LNIS2CuII (LNIS = o-iminobenzosemiquinone), are reported. X-ray crystallog. studies showed that two o-iminobenzosemiquinone radicals form a distorted square-planar geometry around the Cu(II) center of LNIS2CuII. Magnetic measurements revealed the paramagnetic character of the complex caused by the presence of three unpaired electrons located on the o-iminobenzosemiquinonate ligands and the CuII center. Magnetochem. experiments, and EPR and DFT studies prove that the ground state of the complex is a doublet, which is consistent with the ferromagnetic coupling between Cu(II) and o-iminobenzosemiquinone centers and stronger antiferromagnetic coupling between the iminobenzosemiquinone moieties. The ligand-centered redox reactions of the complex were studied by cyclic voltammetry. Aerobic oxidation of alcs. to aldehydes with TEMPO was studied in the presence of LNIS2CuII. Furthermore, LNIS2CuII is an efficient catalyst in homo-coupling of terminal alkynes.
New Journal of Chemistry published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Application of 2-Aminobenzonitrile(Flakes or Chunks).
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts