Xu, Lei published the artcileLn(III)/Chiral Bronsted Acid Catalyzed Asymmetric Cascade Ring Opening/Aza-Piancatelli Rearrangement of D-A Cyclopropanes, Formula: C7H6N2, the main research area is aminocyclopentenone enantioselective synthesis synergistic tandem ring opening Piancatelli rearrangement; synergistic catalyzed cascade ring opening Piancatelli rearrangement cyclopropane aniline.
The first Lewis acid and chiral Bronsted acid cooperatively catalyzed asym. cascade ring opening/aza-Piancatelli rearrangement reaction of furyl-substituted donor-acceptor cyclopropanes is achieved, enabling the construction of functionalized aminocyclopentenones bearing α-quaternary carbon stereocenters in high yields with excellent enantio- and diastereoselectivities under remarkably low catalyst loading of 0.2-1.2 mol %.
Organic Letters published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Formula: C7H6N2.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts