Karmakar, Ujjwal published the artcilePhotocatalytic para-Selective C-H Functionalization of Anilines with Diazomalonates, Application of 2-Aminobenzonitrile(Flakes or Chunks), the main research area is photocatalytic para selective alkylation aniline diazomalonate.
Visible-light-induced para-selective C-H functionalization of anilines over N-H insertion was developed using diazomalonates with the help of an Ir(III) photocatalyst. The para-selective radical-radical cross coupling proceeded via C-centered radical intermediates generated from both anilines and diazomalonates. The photochem. of anilines could be extended to other N-heterocycles, such as indole and carbazole. The reaction pathway for the selective C-C coupling was validated by electrochem. and photophys. experiments as well as computational studies.
Organic Letters published new progress about Alkylation, regioselective (photocatalytic). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Application of 2-Aminobenzonitrile(Flakes or Chunks).
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts