Suresh, Sundaram published the artcileA Study of the Reactions of 3-Bromopropenals with Anilines for the Synthesis of α-Bromo Enaminones, Synthetic Route of 1885-29-6, the main research area is bromo enaminone preparation; aniline chemoselective diastereoselective addition bromopropenal.
A one-pot strategy for the synthesis of α-bromo enaminones is reported. The reactions proceed via the p-toluenesulfonic acid monohydrate catalyzed reactions of 3-bromopropenals with anilines in DMSO and do not require an external brominating agent. The chemoselective 1,2-addition was accomplished by employing aniline with a sterically hindered electron-withdrawing group attached at the ortho-position. In addition, the reactions involving other aniline derivatives as nucleophiles have resulted in minor yields of 1,4-addition product. The 3-bromopropenals showed a diverse range of reactivities with aniline derivatives
Advanced Synthesis & Catalysis published new progress about 1,2-Addition reaction (stereoselective). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Synthetic Route of 1885-29-6.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts