Galani, Sunil M. published the artcileEnhanced Thermocatalytic Activity of Porous Yellow ZnO Nanoflakes: Defect- and Morphology-Induced Perspectives, Application In Synthesis of 100-70-9, the main research area is thermocatalysis porous yellow zinc oxide nanoflake defect morphol; heterogeneous catalysis; nanostructures; oxygen vacancies; tetrazole; zinc oxide.
A simple and effective strategy is reported for the synthesis of yellow ZnO (Y-ZnO) nanostructures with abundant O vacancies on a large scale, through the sulfidation of ZnO followed by calcination. The developed strategy allows retention of the overall morphol. of Y-ZnO compared with pristine ZnO and the extent of O vacancies can be tuned. The influence of O deficiencies, the extent of defect sites, and the morphol. of ZnO on its solution-phase thermocatalytic activity was evaluated in the synthesis of 5-substituted-1H-tetrazoles with different nitriles and Na azide. A reasonable enhancement in the reaction rate was achieved by using Y-ZnO nanoflakes (Y-ZnO NFs) as a catalyst in place of pristine ZnO NFs. The reaction was complete within 6 h at 110° with Y-ZnO NFs, whereas it took 14 h at 120° with pristine ZnO NFs. The catalyst is easy to recycle without a significant loss in catalytic activity.
Chemistry – An Asian Journal published new progress about Catalysis (thermo-). 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Application In Synthesis of 100-70-9.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts