Colvin, Ernest W.’s team published research in Tetrahedron Letters in 23 | CAS: 5098-14-6

Tetrahedron Letters published new progress about 5098-14-6. 5098-14-6 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Salt,Sulfonic acid,Amine,Benzene, name is 2-Aminomalononitrile 4-methylbenzenesulfonate, and the molecular formula is C10H11N3O3S, SDS of cas: 5098-14-6.

Colvin, Ernest W. published the artcileO-(Diphenylphosphinyl)hydroxylamine: a new reagent for electrophilic C-amination, SDS of cas: 5098-14-6, the publication is Tetrahedron Letters (1982), 23(37), 3835-6, database is CAplus.

Ph2P(O)ONH2 (I) efficiently aminated (EtO)2P(O)CH–CO2CH2Ph, (EtO2C)2CH–, (NC)2CH–, PhMgBr, and Me(CH2)5MgBr in THF at -78° under Ar. E.g., treatment of (EtO)2P(O)CH2CO2CH2Ph with NaH at room temperature under Ar, then I at -78° gave 60% (EtO)2P(O)CH(NH2)CO2CH2Ph.

Tetrahedron Letters published new progress about 5098-14-6. 5098-14-6 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Salt,Sulfonic acid,Amine,Benzene, name is 2-Aminomalononitrile 4-methylbenzenesulfonate, and the molecular formula is C10H11N3O3S, SDS of cas: 5098-14-6.

Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts