Maity, Soham published the artcileEfficient and Stereoselective Nitration of Mono- and Disubstituted Olefins with AgNO2 and TEMPO, Quality Control of 5153-73-1, the publication is Journal of the American Chemical Society (2013), 135(9), 3355-3358, database is CAplus and MEDLINE.
Nitroolefins are common and versatile reagents. Their synthesis from olefins is generally limited by the formation of mixtures of cis and trans compounds Here the authors report that silver nitrite (AgNO2) along with TEMPO can promote the regio- and stereoselective nitration of a broad range of olefins. This work discloses a new and efficient approach wherein, starting from olefin, nitroalkane radical formation and subsequent transformations lead to the desired nitroolefin in a stereoselective manner.
Journal of the American Chemical Society published new progress about 5153-73-1. 5153-73-1 belongs to nitriles-buliding-blocks, auxiliary class Nitrile,Alkenyl,Nitro Compound,Benzene, name is (E)-4-(2-Nitrovinyl)benzonitrile, and the molecular formula is C9H6N2O2, Quality Control of 5153-73-1.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts