Wang, Mei-Ling published the artcileMizoroki-Heck Reaction of Unstrained Aryl Ketones via Ligand-Promoted C-C Bond Olefination, COA of Formula: C10H12F6N4O6PdS2, the publication is Organic Letters (2021), 23(6), 2147-2152, database is CAplus and MEDLINE.
Mizoroki-Heck reaction of unstrained aryl ketone with acrylate/styrene was accomplished via palladium-catalyzed ligand-promoted C-C bond cleavage. Various (hetero)aryl ketones were compatible in the reaction, affording the alkene product in good to excellent yields. Further applications in the late-stage olefination of some drugs, natural products, and fragrance-derived aryl ketones demonstrated the synthetic utility of this protocol. By employing ketone as both the directing group and the leaving group, 1,2-bifunctionalization was achieved via sequential ortho-C-H alkylation/ipso-Heck olefination.
Organic Letters published new progress about 68569-14-2. 68569-14-2 belongs to nitriles-buliding-blocks, auxiliary class Palladium, name is Tetrakis(acetonitrile)palladium(II) Ditriflate, and the molecular formula is C38H74Cl2N2O4, COA of Formula: C10H12F6N4O6PdS2.
Referemce:
https://en.wikipedia.org/wiki/Nitrile,
Nitriles – Chemistry LibreTexts