Cathodic behaviour of 1-cycloalken-1-yl phenyl sulfones. I. Competition among dimerization, cleavage, isomerization and oligomerization processes in aprotic media was written by Prigent, Sylvie;Cauliez, Pascal;Simonet, Jacques;Peters, Dennis G.. And the article was included in Acta Chemica Scandinavica in 1999.Application of 4435-14-7 This article mentions the following:
1-Cycloalken-1-yl Ph sulfones (1-cyclopenten-1-yl Ph sulfone and 1-cyclohexen-1-yl Ph sulfone) were studied electrochem. in aprotic media (DMF, DMSO, or acetonitrile containing tetraalkylammonium salts) at a mercury electrode. Their behavior was compared with that of 2-norbornen-2-yl Ph sulfone. The expected cleavage reaction is accompanied by a concomitant isomerization process into allyl sulfones that is triggered by electrogenerated bases. A quant. determination of the product distribution during controlled-potential electrolyzes suggests the formation of dimers and oligomeric species, arising through a Michael addition of the sulfone anions to the activated double bond of these sulfones. In the experiment, the researchers used many compounds, for example, 2-Cyclohexylacetonitrile (cas: 4435-14-7Application of 4435-14-7).
2-Cyclohexylacetonitrile (cas: 4435-14-7) belongs to nitriles. Nitrile compounds can be prepared by the incorporation of a cyanide source through C–C bond formation or by dehydration of primary carboxamides. Nitriles are susceptible to hydrogenation over diverse metal catalysts. The reaction can afford either the primary amine (RCH2NH2) or the tertiary amine ((RCH2)3N), depending on conditions.Application of 4435-14-7
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts