Synthesis of Benzotriazine and Aryltriazene Derivatives Starting from 2-Azidobenzonitrile Derivatives was written by Nakhai, Azadeh;Stensland, Birgitta;Svensson, Per H.;Bergman, Jan. And the article was included in European Journal of Organic Chemistry in 2010.Name: 2-Amino-3,5-dibromobenzonitrile This article mentions the following:
3-Substituted 3,4-dihydro-4-imino-1,2,3-benzotriazine derivatives 7 (e. g. I) were formed from 2-azidobenzonitriles as starting materials on treatment with Grignard or lithium organic reagents. In some cases these procedures gave aryltriazenes, e. g. II and III, as products. All compounds were identified by NMR spectroscopy and the structures of three products, namely I, II and III, were corroborated by X-ray crystallog. In the experiment, the researchers used many compounds, for example, 2-Amino-3,5-dibromobenzonitrile (cas: 68385-95-5Name: 2-Amino-3,5-dibromobenzonitrile).
2-Amino-3,5-dibromobenzonitrile (cas: 68385-95-5) belongs to nitriles. The R-C-N bond angle in and nitrile is 180° which give a nitrile functional group a linear shape. Both the carbon and the nitrogen are sp hydridized which leaves them both with two p orbitals which overlap to form the two π bond in the triple bond. Nitrile groups in organic compounds can undergo a variety of reactions depending on the reactants or conditions. A nitrile group can be hydrolyzed, reduced, or ejected from a molecule as a cyanide ion.Name: 2-Amino-3,5-dibromobenzonitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts