Reshma, G. published the artcileSynthesis and structure of mono and bis {1,3-bis(2-pyridylimino)isoindoline} supported 3d transition metal complexes, Synthetic Route of 91-15-6, the main research area is mono bis pyridyliminoisoindoline transition metal complex preparation; crystal mol structure cobalt bis pyridyliminoisoindoline complex; manganese iron cobalt nickel copper zinc pyridyliminoisoindoline complex preparation.
Series of homoleptic and heteroleptic 3d transition metal complexes were prepared in anal. pure form and high yield, by reacting appropriate metal precursors with 1,3-bis(2-pyridylimino)isoindolate (BPIH) ligand under suitable reaction conditions. The complexes were characterized by various spectro-anal. techniques, including IR, UV, NMR, ESI Mass and x-ray crystal anal. A distorted octahedral structure containing two meridionally coordinating BPI ligands was assigned to all the homoleptic complexes. While, for the heteroleptic complexes, a highly distorted square pyramidal geometry, with a planar tridentate BPI ligand coordinating to the metal center along with chloro and aqua ligands was assigned. Considering the unique structural features of the complexes, potential catalytic applications are envisaged.
Journal of Molecular Structure published new progress about Crystal structure. 91-15-6 belongs to class nitriles-buliding-blocks, name is Phthalonitrile, and the molecular formula is C8H4N2, Synthetic Route of 91-15-6.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts