Yeast supported gold nanoparticles: an efficient catalyst for the synthesis of commercially important aryl amines was written by Krishnan, Saravanan;Patel, Paresh N.;Balasubramanian, Kalpattu K.;Chadha, Anju. And the article was included in New Journal of Chemistry in 2021.Application In Synthesis of 2-Amino-4-(trifluoromethyl)benzonitrile This article mentions the following:
Candida parapsilosis ATCC 7330 supported gold nanoparticles (CpGNP), prepared by a simple and green method was selectively reduce nitroarenes and substituted nitroarenes with different functional groups like halides (-F, -Cl, -Br), olefins, esters and nitriles using sodium borohydride. The product aryl amines which were useful for the preparation of pharmaceuticals, polymers and agrochems. were obtained in good yields (up to >95%) using CpGNP catalyst under mild conditions. The catalyst showed high recyclability (â?0 cycles) and was a robust free flowing powder, stored and used after eight months without any loss in catalytic activity. In the experiment, the researchers used many compounds, for example, 2-Amino-4-(trifluoromethyl)benzonitrile (cas: 1483-54-1Application In Synthesis of 2-Amino-4-(trifluoromethyl)benzonitrile).
2-Amino-4-(trifluoromethyl)benzonitrile (cas: 1483-54-1) belongs to nitriles. Nitrile carbon shifts are in the range of 115â?25 ppm whereas in isonitriles the shifts are around 155â?65 ppm. Asymmetric bioreduction of nitriles is an attractive route to produce optically active nitriles as current metal-catalyzed hydrogenations tend to have low reactivity.Application In Synthesis of 2-Amino-4-(trifluoromethyl)benzonitrile
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts