Mononuclear half-sandwich iridium and rhodium complexes through C-H activation: Synthesis, characterization and catalytic activity was written by Yao, Zi-Jian;Li, Kuan;Li, Peng;Deng, Wei. And the article was included in Journal of Organometallic Chemistry in 2017.HPLC of Formula: 10282-32-3 This article mentions the following:
A series of mononuclear half-sandwich cyclometalated group 9 (Ir and Rh) metal complexes were synthesized in good yields through metal-mediated C-H bond activation. These air-stable C, N-chelate mode complexes have similar solid state structures. Both exptl. results and DFT calculations confirmed that no binuclear complexes were generated in this reaction. The iridium complex 3a exhibited good catalytic activity for the reduction of both electron-rich and electron-poor aryl imines with low catalyst loading in the presence of formic acid/triethylamine (F/T) azeotropic mixture All complexes were fully characterized by elemental anal. and IR and NMR spectroscopies. The structures were further confirmed by single-crystal X-ray anal. In the experiment, the researchers used many compounds, for example, 4-(Benzylamino)benzonitrile (cas: 10282-32-3HPLC of Formula: 10282-32-3).
4-(Benzylamino)benzonitrile (cas: 10282-32-3) belongs to nitriles. Nitrile function is a very important functional group because it can be manipulated to other functional groups such as carboxylic acid by hydrolysis or amine by reduction, respectively. Nitriles are susceptible to hydrogenation over diverse metal catalysts. The reaction can afford either the primary amine (RCH2NH2) or the tertiary amine ((RCH2)3N), depending on conditions.HPLC of Formula: 10282-32-3
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts