Related Products of 1897-52-5, Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. The appropriate choice of redox mediator can avoid electrode passivation and overpotential. 1897-52-5, Name is 2,6-Difluorobenzonitrile, SMILES is N#CC1=C(F)C=CC=C1F, belongs to nitriles-buliding-blocks compound. In a article, author is Xie Jianwei, introduce new discover of the category.
Transition-Metal-Free Decarboxylative Amidation of Aryl alpha-Keto Acids with Diphenylphosphoryl Azide: New Avenue for the Preparation of Primary Aryl Amides
In this paper, a novel transition-metal-free decarboxylative amidation of aryl alpha-keto acids with diphenylphosphoryl azide (DPPA) under mild conditions has been developed. The reaction proceeded smoothly to afford the corresponding primary aryl amide products in good to excellent yields under air and showed excellent functional group tolerance. Gram-scale reaction was also performed to produce the desired product in high yield. In addition, the mechanism of the present reaction was investigated.
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