Related Products of 17524-05-9. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Stable Bimetallene Hydride Boosts Anodic CO Tolerance of Fuel Cells. Author is Wu, Jiandong; Cui, Xiaoqiang; Fan, Jinchang; Zhao, Jingxiang; Zhang, Qinghua; Jia, Guangri; Wu, Qiong; Zhang, Dantong; Hou, Changmin; Xu, Shan; Jiao, Dongxu; Gu, Lin; Singh, David J.; Zheng, Weitao.
Active and durable anode electrocatalysts are of vital importance for practical implementation of fuel cells. However, the surface-adsorbed reaction intermediates, especially CO, easily poison and deactivate the electrocatalysts. Here, we report ultrathin molybdenum-palladium hydride (MoPdH) bimetallene as a high-efficiency electrocatalyst for the methanol oxidation reaction. This exhibits a 6.0-fold enhancement of mass activity relative to com. Pd black catalyst. Alloying with Mo strongly enhances the H binding ability of Pd and thereby stabilizes the MoPdH bimetallene. The resulting ultrathin hydride structure and the stabilization of it by Mo alloying yields a MoPdH bimetallene with the outstanding CO tolerance. The stabilization is understood in terms of the Miedema rule, which thus provides a new opportunity for catalyst design boosting the commercialization of fuel cells based on stable bimetallene hydride nanosheets.
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