Asha, T. M.; Sithambaresan, M.; Prathapachandra Kurup, M. R. published an article about the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9,SMILESS:O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O ).Electric Literature of C10H14MoO6. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:17524-05-9) through the article.
Four new mononuclear dioxidomolybdenum(VI) complexes [MoO2LD] (D = methanol (1), ethanol (2), propanol (3) and [MoO2LD]2·D (D = 4-picoline (4))) were synthesized by the reaction of [MoO2(acac)2] with the thiosemicarbazone (H2L) derived from 3-ethoxy-2-hydroxybenzaldehyde and N4-(3-methoxyphenyl)thiosemicarbazone in presence of donor solvents like methanol, ethanol, propanol and 4-picoline. Crystal and mol. structures of the complexes were determined by single crystal x-ray diffraction anal. All the complexes portrayed similar mononuclear structures where the thiosemicarbazone is bonded to molybdenum(VI) ion as a bineg. tridendate agent. The molybdenum(VI) center in complexes 1-4 is six coordinate by the thiosemicarbazone, two oxido groups and an oxygen or nitrogen atom from the donor solvent mols. The complexes 1-4 exhibit oxygen atom transfer to PPh3 in acetonitrile medium in presence of N-N bidendate donors to form [Mo(IV)OL(N-N)] (N-N = 2-2′ bipyridine (5) or 1,10 phenanthroline (6)). The complexes were further characterized by elemental anal., spectroscopic methods (IR, UV-visible and 1H NMR) and TGA. The electrochem. behavior of these complexes were investigated for an insight into the redox behavior of the molybdenum(VI) centers in these complexes. Hirshfeld surface anal. was successfully employed for exploring the coordination geometries and various noncovalent interactions present in their crystal structures. Also, the catalytic abilities of 1-4 were tested for the oxidation of styrene using aqueous H2O2 as oxidant and NaHCO3 as co-catalyst. The reaction condition for all-out catalytic proficiency of the catalysts 1-4 were examined by studying the effect of various parameters such as the amount of catalyst, H2O2, co-catalyst (NaHCO3) and solvent (CH3CN) as well as temperature of the reaction. Almost 97-98% product selectivity was attained for the oxidation of styrene to styrene oxide.
If you want to learn more about this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Electric Literature of C10H14MoO6, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(17524-05-9).
Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts