Electric Literature of C10H14MoO6. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Single-Site Molybdenum Catalyst for the Synthesis of Fumarate. Author is Jiang, Huifang; Lu, Rui; Si, Xiaoqin; Luo, Xiaolin; Xu, Jie; Lu, Fang.
The catalysts with well-defined mononuclear active sites are expected to develop more active catalytic systems for the key chem. transformations. But the rational design of catalyst with stable mononuclear Mo site is still a crucial challenge because of its oligomerization tendency under reaction condition. Herein, molybdenum catalyst (Mo-8-HQ) with single Mo sites was designed via the pyridine nitrogen and oxygen in hydroxyl of 8-hydroxyquinoline coordinated with Mo atom. The crystal catalyst was stabilized by π-π stacking interaction and hydrogen bonds to form isolated Mo specie. The single-site molybdenum catalyst exhibited excellent catalytic performance in didehydroxylation reactions with high selectively of di-Bu fumarate (86 %) product at mild reaction condition. Deuterium isotopic studies demonstrated that the mechanism feature of didehydroxylation reaction catalyzed by Mo-8-HQ was through concerted cleavage of two C-O bonds process, which could be accelerated by single-site molybdenum catalysts with electron-rich Mo centers.
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts