Hossain, Kamal Md.; Schachner, Joerg A.; Haukka, Matti; Moesch-Zanetti, Nadia C.; Nordlander, Ebbe; Lehtonen, Ari published the article 《Catalytic epoxidation using dioxidomolybdenum(VI) complexes with tridentate aminoalcohol phenol ligands》. Keywords: crystal structure dioxidomolybdenum tridentate aminoalc phenol preparation epoxidation catalyst.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Related Products of 17524-05-9. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.
Reaction of the tridentate aminoalc. phenol ligands 2,4-di-tert-butyl-6-(((2 hydroxyethyl)(methyl)amino)methyl)phenol (H2L1) and 2,4-di-tert-butyl-6-(((1-hydroxybutan-2-yl)amino)methyl)phenol (H2L2) with [MoO2(acac)2] in MeOH solutions gave [MoO2(L1)(MeOH)] (1) and [MoO2(L2)(MeOH)] (3), resp. In contrast, the analogous reactions in MeCN afforded dinuclear [Mo2O2(μ-O)2(L1)2] (2) and [Mo2O2(μ-O)2(L2)2] (4). The corresponding reactions with the potentially tetradentate ligand 3-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)propane-1,2-diol (H3L3) gave mononuclear [MoO2(L3)(MeOH)] (5) in MeOH while in MeCN solution a trinuclear structure [Mo3O3(μ-O)3(L3)3] (6) was obtained. In both cases, the ligand moiety L3 coordinated in a tridentate fashion. The catalytic activities of complexes 1-6 in epoxidation of five different olefins with tert-Bu hydroperoxide and H2O2 were studied. The catalytic activities are moderate to good for the reaction of substrate cis-cyclooctene, while all complexes were less active in the epoxidation of the more challenging substrates. The mol. structures of 1, 2, 4 and 6 were determined by single crystal x-ray diffraction analyses.
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Reference:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts