In 2014,Fuchibe, Kohei; Mayumi, Yuka; Yokota, Misaki; Aihara, Hiromichi; Ichikawa, Junji published 《Indium(III)-catalyzed cationic cyclization of 1,1-difluoroallenes: regioselective synthesis of 1-fluoronaphthalenes》.Bulletin of the Chemical Society of Japan published the findings.Computed Properties of C8H6BrN The information in the text is summarized as follows:
1,1-Difluoroallenes underwent InBr3-catalyzed ring construction via in situ-generated allylic CF2 cations to give 1-fluoronaphthalenes in good yield. DFT calculations suggested that a pos. charge was localized on the CF2 carbon in the key allylic CF2 cation, which was stabilized by α-cation stabilizing effect of the fluorines and hyperconjugation with the adjuscent C-In σ bond.2-(3-Bromophenyl)acetonitrile(cas: 31938-07-5Computed Properties of C8H6BrN) was used in this study.
2-(3-Bromophenyl)acetonitrile(cas: 31938-07-5) has been used in the synthesis of 2-(1-cyano-1-(3-bromophenyl))methylidene-3-phenylthiazolidine-4,5-dione or a series of aminoethylbiphenyls, novel 5-HT7 receptor ligands.Computed Properties of C8H6BrN
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts