Related Products of 31938-07-5In 2021 ,《Silver/manganese dioxide nanorod catalyzed hydrogen-borrowing reactions and tert-butyl ester synthesis》 was published in Journal of Chemical Research. The article was written by Luo, Huanhuan; Yang, Yike; Yang, Bobin; Xu, Zhaojun; Wang, Dawei. The article contains the following contents:
Silver/manganese dioxide (Ag@MnO2) nanorods are synthesized and characterized by SEM, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, and XPS. It was discovered that Ag@MnO2 nanorods can realize hydrogen-borrowing reactions in high yields and are also effective for the synthesis of tert-Bu esters from aryl cyanides and tert-Bu hydroperoxide in a short period of time. Mechanistic experiments revealed that this catalytic system acts as a Lewis acid in hydrogen-borrowing reactions, while the synthesis of tert-Bu esters occurs through a radical pathway. This is the first report on the excellent catalytic activity of Ag@MnO2 nanorods as a catalyst. In the experimental materials used by the author, we found 2-(3-Bromophenyl)acetonitrile(cas: 31938-07-5Related Products of 31938-07-5)
2-(3-Bromophenyl)acetonitrile(cas: 31938-07-5) has been used in the synthesis of a series of aminoethylbiphenyls, novel 5-HT7 receptor ligands or 2-(1-cyano-1-(3-bromophenyl))methylidene-3-phenylthiazolidine-4,5-dione.Related Products of 31938-07-5
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts