Category: nitriles-buliding-blocksIn 2012 ,《Quantitative structure-property relationships studies on free-radical polymerization chain-transfer constants for styrene》 appeared in Journal of Applied Polymer Science. The author of the article were Xu, Jie; Wang, Lei; Zhang, Hui; Shen, Xiaolin; Liang, Guijie. The article conveys some information:
Quant. structure-property relationships (QSPR) studies were performed for kinetic chain-transfer constants of 90 agents on styrene polymerization at 60°. By using stepwise multi-linear regression anal. (MLRA) and artificial neural network (ANN), linear and nonlinear models containing seven descriptors were obtained with R2 of 0.7866 and 0.8661 for the training set, resp. The reliability of the proposed models was validated through the test set. The descriptors involved in the models are related to the mol. conformational changes and some functional groups. As these descriptors are directly calculated from the mol. structure, the proposed models can be employed to estimate the chain-transfer constants for styrene. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. In the experiment, the researchers used many compounds, for example, 2-(3-Bromophenyl)acetonitrile(cas: 31938-07-5Category: nitriles-buliding-blocks)
2-(3-Bromophenyl)acetonitrile(cas: 31938-07-5) has been used in the synthesis of a series of aminoethylbiphenyls, novel 5-HT7 receptor ligands or 2-(1-cyano-1-(3-bromophenyl))methylidene-3-phenylthiazolidine-4,5-dione.Category: nitriles-buliding-blocks
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts