Application of 1194-02-1In 2019 ,《Extending the Chemistry of Hexamethylenetetramine in Ruthenium-Catalyzed Amine Oxidation》 was published in Organometallics. The article was written by Kannan, Muthukumar; Muthaiah, Senthilkumar. The article contains the following contents:
A very efficient, highly atom economical, and environmentally benign oxidation of primary and secondary amines using an in situ catalyst system generated from com. available Ru(II) benzene dichloride dimer and hexamethylenetetramine was demonstrated. Mechanistic studies revealed that hexamethylenetetramine acted as a source of hydride to generate the active Ru hydride catalyst and amine oxidation involves a dehydrogenative pathway. In comparison to reported catalyst systems for the dehydrogenative oxidation of amines, this synthetic protocol makes use of a simple Ru precursor and a cheaper additive; it is very selective, leading to the exclusive formation of nitrile/imine compounds Further, it releases H as the only side product, suggesting the potential application of the developed catalyst system in H storage. In the experimental materials used by the author, we found 4-Fluorobenzonitrile(cas: 1194-02-1Application of 1194-02-1)
4-Fluorobenzonitrile(cas: 1194-02-1) is used as chemical intermediate, solvent for perfumes and pharmaceuticals, stabilizer for chlorinated solvents, HPLC analysis, catalyst and component of transition-metal complex catalysts.Application of 1194-02-1
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts