Jeng, Huey-Jiuan et al. published their research in Journal of the Chinese Chemical Society (Taipei) in 1994 |CAS: 5098-14-6

The Article related to pyrrole derivative, heteroatom substituted acetonitrile reaction, aminomalononitrile reaction carbonyl compound, phenylthiocyclopropanecarbonitrile reaction nucleophile, Heterocyclic Compounds (One Hetero Atom): Pyrroles and Pyrrolizines and other aspects.HPLC of Formula: 5098-14-6

On December 31, 1994, Jeng, Huey-Jiuan; Fang, Jim-Min published an article.HPLC of Formula: 5098-14-6 The title of the article was Formation of pyrrole derivatives from heteroatom-substituted acetonitriles. And the article contained the following:

Aminomalononitrile reacted with conjugated carbonyl compounds to give 3H-pyrrolines. Treatment of 2-chloro-2-phenylthioacetonitrile with alkenes in the presence of potassium t-butoxide afforded 1-phenylthiocyclopropanecarbonitriles, which reacted with nucleophiles in 1,2-, 1,4- or 1,6-addition modes. The 1,2-adducts (cyclopropylimines) rearranged in situ to give substituted pyrroles. The experimental process involved the reaction of 2-Aminomalononitrile 4-methylbenzenesulfonate(cas: 5098-14-6).HPLC of Formula: 5098-14-6

The Article related to pyrrole derivative, heteroatom substituted acetonitrile reaction, aminomalononitrile reaction carbonyl compound, phenylthiocyclopropanecarbonitrile reaction nucleophile, Heterocyclic Compounds (One Hetero Atom): Pyrroles and Pyrrolizines and other aspects.HPLC of Formula: 5098-14-6

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts