Wang, Zhen published the artcileElemental Sulfur-Promoted Aerobic Dehydrogenative Aromatization of Cyclohexanones with Amines, Name: 2-Aminobenzonitrile(Flakes or Chunks), the main research area is dialkyl phenylenediamine naphthylamine preparation; cyclohexanone amine aerobic dehydrogenative aromatization sulfur.
Herein, an elemental sulfur-promoted aerobic dehydrogenation system for the synthesis of N,N’-dialkyl-o-phenylenediamines I (R = H, Me, C6H5, etc.; R1 = i-Pr, c-hexyl, c-pentyl, etc.) and N-substituted 2-naphthylamines II (R1 = c-hexyl, C6H5, 4-ClC6H4, etc.) is reported . Readily available cyclohexanones and amines (especially alkylamines) are transformed smoothly to target products. Aromatic amines can be achieved from all aliphatic reagents under aerobic metal-free reaction conditions. Control reactions show that the combinational use of elemental sulfur and mol. oxygen is exceptionally essential for this dehydrogenative aromatization.
Journal of Organic Chemistry published new progress about Aromatic amines Role: SPN (Synthetic Preparation), PREP (Preparation) (naphthylamines). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Name: 2-Aminobenzonitrile(Flakes or Chunks).
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts