Kurosawa, Miki B. published the artcileUnified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones, HPLC of Formula: 42872-30-0, the main research area is diarylketone palladium catalyst reduction; diarylmethane preparation; oxomethyldiarene palladium catalyst reduction dimerization; tetraarylethane preparation; triarylmethane preparation.
A deoxygenative transformation of diarylketones leading to multiply arylated alkanes was developed. Diarylketones were reacted with diphenylphosphine oxide resulting in a phospha-Brook rearrangement, followed by palladium-catalyzed cross-couplings or a Friedel-Crafts type alkylation to afford the corresponding multiply arylated alkanes. A variety of diarylketones was converted to multiply arylated alkanes such as diarylmethanes, tetraarylethanes and triarylmethanes by reduction, dimerization and arylation in one pot. Furthermore, a one-pot conversion from arylcarboxylic acids to diarylmethanes and tetraarylethanes and a synthesis of tetraarylmethane and triphenylethane using sequential coupling reactions were also presented.
Chemical Science published new progress about Aryl ketones Role: RCT (Reactant), RACT (Reactant or Reagent). 42872-30-0 belongs to class nitriles-buliding-blocks, name is 2-(3-Benzoylphenyl)propanenitrile, and the molecular formula is C16H13NO, HPLC of Formula: 42872-30-0.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts