Sojka, Martin published the artcileBifurcated hydrogen bonds in platinum(II) complexes with phosphinoamine ligands, Recommanded Product: 2-Aminobenzonitrile(Flakes or Chunks), the main research area is platinum phosphinoamine chloro complex preparation conformational energy DFT; crystal structure platinum phosphinoamine chloro.
In this work we report an investigation of the influence of bifurcated intramol. hydrogen bonds on conformations of platinum(II) complexes with phosphinoamine ligands. The series of new cis and trans-PtCl2L2 complexes with phosphinoamine ligands was synthesized and characterized by 1H, 31P, 195Pt NMR, IR, and mol. structures of 8 complexes were determined by X-ray crystallog. The hydrogen bonds are observed between NH···ClPt and NH···R (R = COOCH3, C(O)CH3, F, CN) moieties of the ligands and Pt core. The structural data from X-ray diffraction are linked to calculated conformational energies from d. functional theory (DFT) and topol. anal. results obtained from quantum theory of atoms in mols. (QTAIM) calculations The most prominent NH···ClPt interactions are found in the cis complexes with para substituted phosphinoamine ligands, which show delocalization indexes (DI) up to 0.09. The ortho substituted phosphinoamine ligands decrease the DI values down to zero for C(O)OCH3 and C(O)CH3 moieties.
Polyhedron published new progress about phosphinoamines). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Recommanded Product: 2-Aminobenzonitrile(Flakes or Chunks).
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts