Vorobyev, P. B.’s team published research in Khimicheskii Zhurnal Kazakhstana in 2019-06-30 | CAS: 100-70-9

Khimicheskii Zhurnal Kazakhstana published new progress about Acids Role: FMU (Formation, Unclassified), FORM (Formation, Nonpreparative). 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Application of Picolinonitrile.

Vorobyev, P. B. published the artcileRole of theory acids and bases in the forming concepts of the mechanism catalytic oxidation and oxidative ammonolysis, Application of Picolinonitrile, the main research area is methyl pyridine catalytic oxidation oxidative ammonolysis.

Exptl. data of oxidation and oxidative ammonolysis the isomeric methylpyridines in the presence of vanadium oxide catalysts, it was found that the reactivity of substrates increases in the following sequence: 3-methylpyridine < 2-methylpyridine < 4-methylpyridine. The obtained exptl. results of relative reactivity of initial compounds were interpreted by the theory of acids and bases. It was shown that among the isomeric methylpyridines, increase of basicity which influence to adsorpting ability in the same order as the basicity and the CH-acidity of substrates calculated using non-empirical quantumchem. methods. Khimicheskii Zhurnal Kazakhstana published new progress about Acids Role: FMU (Formation, Unclassified), FORM (Formation, Nonpreparative). 100-70-9 belongs to class nitriles-buliding-blocks, name is Picolinonitrile, and the molecular formula is C6H4N2, Application of Picolinonitrile.

Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts