Liu, Jingya published the artcileMn(III)-Catalyzed cascade cyclization reaction of o-acyl aromatic isocyanides with boronic acids, Related Products of nitriles-buliding-blocks, the main research area is hydroxyindolenine preparation; acylarom isocyanide preparation boronic acid tandem heterocyclization manganese catalyst.
A Mn(III)-catalyzed cascade cyclization of o-acyl aromatic isocyanides 2-CN-R1C6H3C(O)R2 (R1 = H, 4-F, 3-Me, 2-Cl, etc.; R2 = Me, 2-isocyano-5-methylphenyl, 5-chloro-2-isocyanophenyl, 2-isocyanophenyl) with boronic acids R3B(OH)2 (R3 = Ph, naphthalen-1-yl, thiophen-2-yl, etc.) was carried out via a single-step route to generate a series of 3-hydroxyindolenines I under mild conditions. A plausible mechanism involving a cascade transmetalation, nucleophilic addition and intramol. cyclization sequence was proposed and confirmed. In addition, the reaction procedure featured simple synthesis, wide substrate scope, and excellent functional group compatibility.
Organic Chemistry Frontiers published new progress about Arylboronic acids Role: RCT (Reactant), RACT (Reactant or Reagent). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Related Products of nitriles-buliding-blocks.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts