Sudharsan, Murugesan published the artcilePalladium Nanoparticles Incorporated Thiazoline Functionalized Periodic Mesoporous Organosilica: Efficient Catalyst for Selective Hydrogenation & Csp2-Csp2 Bond Formation Reactions, Category: nitriles-buliding-blocks, the main research area is palladium thiazoline nanocatalyst preparation hydrogenation bond formation reaction.
Thiazoline functionalized periodic mesoporous organosilica (TPMO) supported palladium nanoparticles (Pd-TPMO) were fabricated through a co-condensation approach and successive incorporation of palladium nanoparticles using a double-solvent technique. The TPMO and Pd-TPMO were characterized through 29Si MAS NMR, FTIR, SAXS, XPS, FESEM, TEM and N2 adsorption-desorption, which revealed the morphol. and physicochem. properties of the materials. The catalytic performance of Pd-TPMO was evaluated for hydrogenation of industrially important compounds such as styrene epoxide, furfural, nitrobenzene and Csp2-Csp2 bond-formation reactions. The Pd-TPMO mediated catalytic reactions were found to be effective in producing the corresponding products such as 2-phenylethanol, furfuryl alc., aniline with excellent yields and selectivity. The size and stability of palladium nanoparticles within the confined organosilica framework promotes excellent activity and recyclability of the catalyst without a significant loss in the yields for hydrogenation and Csp2-Csp2 bond-formation reactions.
ChemistrySelect published new progress about Aryl bromides Role: RCT (Reactant), RACT (Reactant or Reagent). 1885-29-6 belongs to class nitriles-buliding-blocks, name is 2-Aminobenzonitrile(Flakes or Chunks), and the molecular formula is C7H6N2, Category: nitriles-buliding-blocks.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts