Ban, Yong-Liang published the artcileThiocyanate radical mediated dehydration of aldoximes with visible light and air, COA of Formula: C9H9NO2, the main research area is nitrile preparation; aldoxime thiocyanate radical dehydration visible light air aizenuranine catalyst.
Herein, a new means of activating aldoximes by an in situ generated thiocyanate radical from ammonium thiocyanate and mol. oxygen at room temp has been discussed. With a catalytic amount of organic dye aizenuranine as the photocatalyst, the dehydration of aldoximes proceeds smoothly under visible light irradiation, providing a simple to handle, excellent functional group tolerance, and metal-free protocol for a wide range of nitriles.
Chemical Communications (Cambridge, United Kingdom) published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 5653-62-3 belongs to class nitriles-buliding-blocks, name is 2,3-Dimethoxybenzonitrile, and the molecular formula is C9H9NO2, COA of Formula: C9H9NO2.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts