Talukdar, Ranadeep published the artcileIrIII-Catalyzed direct syntheses of amides and esters using nitriles as acid equivalents: a photochemical pathway, HPLC of Formula: 91-15-6, the main research area is amide preparation photochem; amine nitrile amidation iridium photocatalyst; ester preparation photochem; nitrile alc esterification iridium photocatalyst.
An unprecedented IrIII[df(CF3)ppy]2(dtbbpy)PF6-catalyzed simple photochem. process for direct addition of amines RNHR1 [R = H, iso-Pr, benzyl, 4-methoxyphenyl, Bu, adamantan-1-yl; R1 = H, iso-Pr, benzyl, hydroxyethyl; RR1 = -(CH2)4-, -(CH2)5-, -(CH2)2O(CH2)2-] and alcs. R2OH (R2 = Bu, cyclohexyl, benzyl, indol-1-yl, etc.) to the relatively less reactive nitrile triple bond is described herein. Various amides RN(R1)C(O)R3 (R3 = Me, cyclohexyl, Ph, pyridin-4-yl, etc.) and esters R2OC(O)R3 are synthesized as the reaction products, with nitriles R3CN being the acid equivalent A mini-library of different types of amides and esters is made using this mild and efficient process, which uses only 1 mol% of photocatalyst under visible light irradiation (λ = 445 nm). The reaction strategy is also efficient for gram-scale synthesis.
New Journal of Chemistry published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 91-15-6 belongs to class nitriles-buliding-blocks, name is Phthalonitrile, and the molecular formula is C8H4N2, HPLC of Formula: 91-15-6.
Referemce:
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts