Category: 17524-05-9

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Journal of Physics and Chemistry of Solids called Surface functionalization of graphene oxide and graphene oxide-magnetite nanocomposite with molybdenum-bidentate Schiff base complex, Author is Masteri-Farahani, M.; Ghahremani, M., which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, Application In Synthesis of Bis(acetylacetonato)dioxomolybdenum(VI).

Surface functionalization of graphene oxide and magnetite-graphene oxide nanocomposite produced new heterogeneous molybdenum catalysts for the epoxidation of olefins. First, graphene oxide was covalently modified with 3-aminopropyl triethoxysilane and thiophene-2-carbaldehyde to achieve graphene oxide supported bidentate Schiff base ligand. Then, reaction of the supported ligand with MoO2(acac)2 complex produced heterogeneous molybdenum catalyst. Moreover, a magnetically separable heterogeneous catalyst was prepared by conjugation of the graphene oxide with magnetite nanoparticles through the click reaction and similar modification of the obtained support with molybdenum-Schiff base complex. The second catalyst can be easily recovered with using an external magnet. The prepared catalysts were characterized with various physicochem. methods. Catalytic activities of the obtained catalysts were evaluated in the epoxidation of olefins with tert-butylhydroperoxide which showed excellent catalytic efficiencies. The catalysts were consecutively reused five times without loss of their activities.

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Safety of Bis(acetylacetonato)dioxomolybdenum(VI). The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Ag@MoS2 Core-Shell Heterostructure as SERS Platform to Reveal the Hydrogen Evolution Active Sites of Single-Layer MoS2. Author is Chen, Junze; Liu, Guigao; Zhu, Yue-zhou; Su, Min; Yin, Pengfei; Wu, Xue-jun; Lu, Qipeng; Tan, Chaoliang; Zhao, Meiting; Liu, Zhengqing; Yang, Weimin; Li, Hai; Nam, Gwang-Hyeon; Zhang, Liping; Chen, Zhenhua; Huang, Xiao; Radjenovic, Petar M.; Huang, Wei; Tian, Zhong-qun; Li, Jian-feng; Zhang, Hua.

Understanding the reaction mechanism for the catalytic process is essential to the rational design and synthesis of highly efficient catalysts. MoS2 has been reported to be an efficient catalyst toward the electrochem. hydrogen evolution reaction (HER), but it still lacks direct exptl. evidence to reveal the mechanism for MoS2-catalyzed electrochem. HER process at the at. level. In this work, we develop a wet-chem. synthetic method to prepare the single-layer MoS2-coated polyhedral Ag core-shell heterostructure (Ag@MoS2) with tunable sizes as efficient catalysts for the electrochem. HER. The Ag@MoS2 core-shell heterostructures are used as ideal platforms for the real-time surface-enhanced Raman spectroscopy (SERS) study owing to the strong electromagnetic field generated in the plasmonic Ag core. The in situ SERS results provide solid Raman spectroscopic evidence proving the S-H bonding formation on the MoS2 surface during the HER process, suggesting that the S atom of MoS2 is the catalytic active site for the electrochem. HER. It paves the way on the design and synthesis of heterostructures for exploring their catalytic mechanism at at. level based on the in situ SERS measurement.

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Hossain, Kamal Md.; Schachner, Joerg A.; Haukka, Matti; Moesch-Zanetti, Nadia C.; Nordlander, Ebbe; Lehtonen, Ari published the article 《Catalytic epoxidation using dioxidomolybdenum(VI) complexes with tridentate aminoalcohol phenol ligands》. Keywords: crystal structure dioxidomolybdenum tridentate aminoalc phenol preparation epoxidation catalyst.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Related Products of 17524-05-9. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.

Reaction of the tridentate aminoalc. phenol ligands 2,4-di-tert-butyl-6-(((2 hydroxyethyl)(methyl)amino)methyl)phenol (H2L1) and 2,4-di-tert-butyl-6-(((1-hydroxybutan-2-yl)amino)methyl)phenol (H2L2) with [MoO2(acac)2] in MeOH solutions gave [MoO2(L1)(MeOH)] (1) and [MoO2(L2)(MeOH)] (3), resp. In contrast, the analogous reactions in MeCN afforded dinuclear [Mo2O2(μ-O)2(L1)2] (2) and [Mo2O2(μ-O)2(L2)2] (4). The corresponding reactions with the potentially tetradentate ligand 3-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)propane-1,2-diol (H3L3) gave mononuclear [MoO2(L3)(MeOH)] (5) in MeOH while in MeCN solution a trinuclear structure [Mo3O3(μ-O)3(L3)3] (6) was obtained. In both cases, the ligand moiety L3 coordinated in a tridentate fashion. The catalytic activities of complexes 1-6 in epoxidation of five different olefins with tert-Bu hydroperoxide and H2O2 were studied. The catalytic activities are moderate to good for the reaction of substrate cis-cyclooctene, while all complexes were less active in the epoxidation of the more challenging substrates. The mol. structures of 1, 2, 4 and 6 were determined by single crystal x-ray diffraction analyses.

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HPLC of Formula: 17524-05-9. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Unraveling the Beneficial Microstructure Evolution in Pyrite for Boosted Lithium Storage Performance. Author is Wang, Jie; Qin, Jinwen; Jiang, Yan; Mao, Baoguang; Wang, Xin; Cao, Minhua.

Pyrite FeS2 as a high-capacity electrode material for lithium-ion batteries (LIBs) is hindered by its unstable cycling performance owing to the large volume change and irreversible phase segregation from coarsening of Fe. Here, the beneficial microstructure evolution in MoS2-modified FeS2 is unraveled during the cycling process; the microstructure evolution is responsible for its significantly boosted lithium storage performance, making it suitable for use as an anode for LIBs. Specifically, the FeS2/MoS2 displays a long cycle life with a capacity retention of 116% after 600 cycles at 0.5 A g-1, which is the best among the reported FeS2-based materials so far. A series of electrochem. tests and structural characterizations substantially revealed that the introduced MoS2 in FeS2 experiences an irreversible electrochem. reaction and thus the in situ formed metallic Mo could act as the conductive buffer layer to accelerate the dynamics of Li+ diffusion and electron transport. More importantly, it can guarantee the highly reversible conversion in lithiated FeS2 by preventing Fe coarsening. This work provides a fundamental understanding and an effective strategy towards the microstructure evolution for boosting lithium storage performances for other metal sulfide-based materials.

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Electric Literature of C10H14MoO6. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Single-Site Molybdenum Catalyst for the Synthesis of Fumarate. Author is Jiang, Huifang; Lu, Rui; Si, Xiaoqin; Luo, Xiaolin; Xu, Jie; Lu, Fang.

The catalysts with well-defined mononuclear active sites are expected to develop more active catalytic systems for the key chem. transformations. But the rational design of catalyst with stable mononuclear Mo site is still a crucial challenge because of its oligomerization tendency under reaction condition. Herein, molybdenum catalyst (Mo-8-HQ) with single Mo sites was designed via the pyridine nitrogen and oxygen in hydroxyl of 8-hydroxyquinoline coordinated with Mo atom. The crystal catalyst was stabilized by π-π stacking interaction and hydrogen bonds to form isolated Mo specie. The single-site molybdenum catalyst exhibited excellent catalytic performance in didehydroxylation reactions with high selectively of di-Bu fumarate (86 %) product at mild reaction condition. Deuterium isotopic studies demonstrated that the mechanism feature of didehydroxylation reaction catalyzed by Mo-8-HQ was through concerted cleavage of two C-O bonds process, which could be accelerated by single-site molybdenum catalysts with electron-rich Mo centers.

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Mohammadikish, Maryam; Yarahmadi, Sana; Molla, Fatemeh researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Synthetic Route of C10H14MoO6.They published the article 《A new water-insoluble coordination polymer as efficient dye adsorbent and olefin epoxidation catalyst》 about this compound( cas:17524-05-9 ) in Journal of Environmental Management. Keywords: efficient dye adsorbent olefin epoxidation catalyst; Coordination polymer; Dye adsorption; Epoxidation; Heterogeneous catalyst; Molybdenum; Zinc. We’ll tell you more about this compound (cas:17524-05-9).

A new water-insoluble bi-metallic coordination polymer was simply prepared via polymerization-precipitation of molybdenum complex building blocks with Zn2+ cation. The linker was a di-carboxylic acid consisting of two coordination sites i.e. N,O and COO- suitable for coordinating to MoO2 unit and Zn2+, resp. Characterization of the prepared coordination polymer was carried out with various physicochem. methods which confirmed the proposed structure. The prepared coordination polymer preferentially adsorbed methylene blue (more than 92% of methylene blue after 2 min) relative to methyl orange and can be reused at least four times without any loss of adsorption efficiency. The adsorption process of both dyes followed the pseudo-second order kinetic equation. Addnl., the obtained coordination polymer catalyzed epoxidation of olefins with tert-butylhydroperoxide (TBHP) quant. with excellent selectivity (>99%) under mild reaction conditions.

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HPLC of Formula: 17524-05-9. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Crystal structures and supramolecular architectures of ONO donor hydrazone and solvent exchangeable dioxidomolybdenum(VI) complexes derived from 3,5-diiodosalicyaldehyde-4-methoxybenzoylhydrazone: Hirshfeld surface analysis and interaction energy calculations. Author is Kuriakose, Daly; Kurup, M. R. Prathapachandra.

A tridentate ONO donor aroylhydrazone, 3,5-diiodosalicyaldehyde-4-methoxybenzoylhydrazone (H2DSMB), and two of its cis-MoO2 complexes, [MoO2(DSMB)(H2O)](DMF)2 (1) and [MoO2(DSMB)(py)] (2), have been synthesized and characterized by different physico-chem. methods. The mol. structures were determined by single crystal x-ray diffraction studies. The aroylhydrazone H2DSMB crystallizes in a monoclinic space group with two identical mols. in the asym. unit. The complex [MoO2(DSMB)(H2O)](DMF)2 (1) crystallizes in a triclinic space group whereas the other complex, [MoO2(DSMB)(py)] (2), crystallizes in an orthorhombic crystal system. The distorted octahedral geometry around the Mo(VI) central atom is satisfied by the di-deprotonated dianionic hydrazone moiety and two oxido oxygen atoms, the sixth labile coordination site being occupied by oxygen/nitrogen atoms from solvent mols. The importance of van der Waals interactions in the formation of the elementary structure obtained from the single crystal x-ray diffraction was authenticated by Hirshfeld surface anal. The individual types of intermol. contacts and their impact on the crystal packing was investigated by the anal. of the Hirshfeld surfaces and the signatures on the two-dimensional fingerprint plots. Interaction energy calculations reveal that the dispersion energy framework is dominant over other energy frameworks. The thermal behavior and the nature of the water mol. in the complex [MoO2(DSMB)(H2O)](DMF)2 (1) is discussed. Furthermore, in vitro cytotoxicity studies of the synthesized aroylhydrazone and its Mo(VI) complexes against the lymphoma ascites cell line are also included.

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So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Mohammadikish, Maryam; Hashemi, S. Hasan researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).HPLC of Formula: 17524-05-9.They published the article 《Functionalization of magnetite-chitosan nanocomposite with molybdenum complexes: new efficient catalysts for epoxidation of olefins》 about this compound( cas:17524-05-9 ) in Journal of Materials Science. Keywords: chitosan coated magnetite molybdenum schiff base olefin epoxidation catalyst. We’ll tell you more about this compound (cas:17524-05-9).

Functionalization of magnetite-chitosan core-shell-type nanocomposite with molybdenum-Schiff base complex through a simple step-by-step path results in the preparation of new catalysts for the epoxidation of olefins. The functionalized nanocomposites were characterized by Fourier-transform IR spectroscopy, X-ray diffractometry, energy-dispersive X-ray spectroscopy, SEM and vibrating-sample magnetometry. Finally, their abilities to catalyze the epoxidation of olefins with tert-Bu hydroperoxide in chloroform were evaluated. It was found that the prepared functionalized nanocomposites have high catalytic activities for heterogeneous epoxidation of olefins with epoxide as the main product in all cases. In particular, when the cyclooctene was employed as olefin, complete conversion and selectivity for epoxycyclooctene and high turnover frequency were obtained at 60 °C. The functionalized nanocomposites can be easily separated magnetically for reusing, and no activity loss was observed in five consecutive runs.

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The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ) is researched.SDS of cas: 17524-05-9.Xie, Sanmu; Wang, Hongkang; Yao, Tianhao; Wang, Jinkai; Wang, Chundong; Shi, Jian-Wen; Han, Xiaogang; Liu, Tianxi; Cheng, Yonghong published the article 《Embedding CoMoO4 nanoparticles into porous electrospun carbon nanofibers towards superior lithium storage performance》 about this compound( cas:17524-05-9 ) in Journal of Colloid and Interface Science. Keywords: cobalt molybdate nanoparticle electrospinning carbon nanofiber lithium storage; CoMoO(4); Electrospinning; Lithium ion batteries; Porous carbon nanofibers; Superior electrochemical properties. Let’s learn more about this compound (cas:17524-05-9).

CoMoO4 nanoparticles have been successfully in-situ formed and simultaneously embedded within the porous carbon nanofibers (CoMoO4/CNFs) via a facile electrospinning-annealing strategy. The porous CoMoO4/CNFs exhibit a sp. surface area of 255.3 m2/g and a pore volume of 0.52 cc/g with average pore diameter of 43.5 nm. The carbon content in the CoMoO4/CNFs can be readily controlled by adjusting the annealing temperature When examined as anode materials for lithium ion batteries (LIBs), the CoMoO4/CNFs demonstrate superior electrochem. performance, delivering a high reversible capacity of 802 mA h/g after 200 cycles at 200 mA/g and a high-rate capacity of 574 mA h/g at 2000 mA/g. The excellent lithium storage behavior can be attributed to the incorporation of CoMoO4 nanoparticles into the porous N-doped graphitic carbon nanofibers, which efficiently buffer the volume changes of CoMoO4 upon lithiation/delithiation and maintain the overall electrode conductivity/integrity.

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Inorganica Chimica Acta called Dioxidomolybdenum(VI) and dioxidouranium(VI) complexes as functional mimic of haloperoxidases catalytic activity in presence of H2O2-KBr-HClO4, Author is Maurya, Mannar R.; Mengesha, Bekele; Maurya, Shailendra K.; Sehrawat, Nidhi; Avecilla, Fernando, which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, Computed Properties of C10H14MoO6.

The stable dibasic tetradentate ligand 1,4-bis-(2-hydroxy-3,5-dimethylbenzyl)piperazine (H2pip-2,4-dmp) prepared by reacting 2,4-dimethylphenol with piperazine in the presence of formaldehyde reacts with [MoVIO2(acac)2] and [UVIO2(CH3COO)2] in equimolar ratio to give neutral hexa-coordinated [MoVIO2(pip-2,4-dmp)] (1) and hepta-coordinated [UVIO2(pip-2,4-dmp)(MeOH)] (2), resp. After characterizing these complexes by spectroscopic (IR, UV/Vis, 1H and 13C NMR) data, elemental and thermal analyses (and single crystal X-ray diffraction study of uranium complex), they are used as catalysts to study the oxidative bromination of thymol. Such catalytic reactions are observed by many model vanadium complexes and are considered as a functional mimic of haloperoxidases. The catalytic oxidation resulted in the formation of three products namely, 2-bromothymol, 4-bromothymol and 2,4-dibromothymol. The optimized reaction conditions are obtained considering concentration of KBr, HClO4, and oxidant for the maximum yield of brominated products. Under the optimized reaction conditions, the product selectivity for both the prepared complexes is investigated. They are found to be competent homogeneous catalysts to afford the products in good yield.

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