Category: 17524-05-9

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about Hierarchical MoS2/NiCo2S4@C urchin-like hollow microspheres for asymmetric supercapacitors, the main research direction is hierarchical molybdenum sulfide nickel cobalt sulfur carbon; urchin hollow microsphere asym supercapacitor.Formula: C10H14MoO6.

Metal sulfides are intensively studied as one of the most predominant materials for supercapacitors owing to such unique advantages as low-cost, low electronegativity and high electrochem. activity, and the appropriate architecture of hybrid metal sulfides is believed to be very effective for fully utilizing their material merits and breaking through their limits of the low-rate capability and inferior cycling stability in supercapacitor applications. Here, a high-performance supercapacitor based on C-coated MoS2/NiCo2S4 urchin-like hollow hybrid microspheres (MoS2/NiCo2S4@C HMSs) is prepared by a facile self-template method. The high specific capacity of 250 mAh/g at 2 A/g and ultra-high rate capability of 91.1% at 40 A/g achieved with the resultant MoS2/NiCo2S4@C HMSs due to their hierarchical hollow hybrid structure and the protection from the coated C thin layer. With the MoS2/NiCo2S4@C HMSs as the pos. electrode and active C as the neg. electrode, asym. supercapacitors (ASCs) have been assembled, which exhibit a high energy d. of 53.01 Wh/Kg at the power d. of 4.20 KW/Kg, an energy d. of 36.46 Wh/Kg even at the ultra-high power d. of 73.75 KW/Kg, and excellent cycling stability of 90.1% after 10,000 cycles of charge-discharge tests at the c.d. of 10 A/g.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Selective oxidation of benzyl alcohols to benzaldehydes catalyzed by dioxomolybdenum Schiff base complex: synthesis, spectral characterization, crystal structure, theoretical and computational studies.Recommanded Product: Bis(acetylacetonato)dioxomolybdenum(VI).

A novel dioxomolybdenum Schiff base complex, compound I, was synthesized by treating MoO2(acac)2 with an ONO donor Schiff base ligand 4-amino-N’-(2-hydroxy-3-methoxybenzylidene)benzohydrazide derived by the condensation of 4-aminobenzohydrazide and 3-methoxysalicylaldehyde. Single-crystal X-ray anal. was also accomplished to ensure the mol. structure of the complex. The geometry around the central metal atom in compound I was distorted octahedral as revealed by the data collected from diffraction studies. Theor. calculations of the synthesized compounds were carried out by DFT at B3LYP/Def2-TZVP level of theory, which showed a good correlation with the exptl. findings. Moreover, the homogeneous catalytic efficiency of the complex was investigated by the process of selective oxidation of benzylic alcs. using urea hydrogen peroxide (UHP) in acetonitrile under reflux conditions.

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The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis(acetylacetonato)dioxomolybdenum(VI)(SMILESS: O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O,cas:17524-05-9) is researched.COA of Formula: C6Cl2N4. The article 《Novel oxovanadium and dioxomolybdenum complexes of tridentate ONO-donor Schiff base ligand: Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity for the selective oxidation of benzylic alcohols》 in relation to this compound, is published in Inorganica Chimica Acta. Let’s take a look at the latest research on this compound (cas:17524-05-9).

Two new oxovanadium and dioxomolybdenum Schiff base complexes, [VVO(L)(OCH3)(CH3OH)] and [MoVIO2(L)(CH2CH3OH)], were synthesized by treating an ONO-donor type Schiff base ligand (H2L) derived by condensation of 5-nitrosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)2 and MoO2(acac)2], resp. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, multinuclear (1H, 13C) NMR, elemental anal. and the most authentic single crystal X-ray diffraction anal. In both complexes the geometry around the central metal ions was distorted octahedral as revealed by the data collected from diffraction studies. Theor. calculation of the synthesized compounds were carried out by DFT as well as TD-DFT using B3LYP method by employing the Def2-TZVP basis set. The findings of theor. data indicated that the calculated results are in accordance with the exptl. findings. Moreover, the catalytic efficiencies of both complexes were investigated by oxidizing the benzylic alcs. in the presence of urea hydrogen peroxide (UHP) in acetonitrile.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Ultrathin g-C3N4/Mo:BiVO4 photoanode for enhanced photoelectrochemical water oxidation, published in 2019-12-31, which mentions a compound: 17524-05-9, mainly applied to ultrathin graphitic carbon nitride molybdenum bismuth vanadium oxide photoanode; molybdenum bismuth vanadium oxide photoanode photoelectrochem water oxidation, Computed Properties of C10H14MoO6.

A g-C3N4/Mo:BiVO4 (CMB) heterojunction photoanode is constructed with enhanced photoelectrochem. (PEC) water oxidation performance, in which ultrathin g-C3N4 is coated on Mo-doped BiVO4. CMB shows a remarkable water oxidation photocurrent of 3.11 mA/cm2 at 1.23 V vs. RHE, which is 3.21 times higher than pristine BiVO4. The maximal incident photon-to-current efficiency (IPCE) reaches 45.5% at 430 nm and the applied bias photo-to-current efficiency (ABPE) reaches 0.74% at 0.78 V vs. RHE, which are 2.62 and 5.76 times compared with pristine BiVO4, resp. The amounts of H and O generated by CMB are 18.58 and 9.32 μmol within 1 h, which are 4.66 and 5.51 times higher than pristine BiVO4. The significant enhancements are attributed to the improvement of charge separation and acceleration of O evolution reaction (OER) kinetics. Mo-dopant enhances charge separation due to its excellent electron transfer capability. Ultrathin g-C3N4 also boosts charge separation via forming a heterojunction with Mo:BiVO4 and promotes OER kinetics by accelerating the transfer of holes to the photoelectrode surface. The work testifies the promise of combing metal-doping with constructing heterojunctions using ultrathin g-C3N4 to enhance water oxidation performance, and provides an excellent reference for designing and constructing efficient photoanodes for PEC water oxidation

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about Guidelines for the Molybdenum Oxidation State and Geometry from X-ray Absorption Spectroscopy at the Mo L2,3-Edges, the main research direction is molybdenum oxidation state geometry X ray absorption spectroscopy.Recommanded Product: 17524-05-9.

Molybdenum accepts oxidation states from -II to +VI. This versatility is highly beneficial for applications in catalysis, especially combined with sulfur to form the ubiquitous MoS2 material. X-ray absorption near-edge structure (XANES) is a particularly well-adapted technique to study simultaneously both elements since the K-edge of S (2472 eV) and the L2,3-edges of Mo (2520-2625 eV) have similar absorption energies. It provides information on both the electronic and local structures of metal-containing species and allows drawing structure-activity relationships. However, L2,3-edges are difficult to interpret, especially for 4d and 5d transition metals. In addition, only a few recent studies focus on the measurement of the signal of Mo-based reference compounds, meaning that the references from the literature do not benefit from recent tech. progress. Notwithstanding theor. tools that allow a deep understanding of such spectroscopic data, the lack of reference spectra prevents a quick yet reliable interpretation. In this work, we provide a method for the interpretation of X-ray absorption near-edge structure (XANES) data at the Mo L2,3-edges based on a library of spectra of simple Mo compounds From our anal., we suggest using the L3-edge to determine the oxidation state (in selected cases) and the L2-edge to gain insight on the geometry around Mo atoms. This method is then applied to a series of molybdenum sulfide compounds to rationalize their structures. Besides this example, these guidelines should help to qual. interpret XANES of Mo at L2,3-edges in future studies.

Compound(17524-05-9)Recommanded Product: 17524-05-9 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Bis(acetylacetonato)dioxomolybdenum(VI)), if you are interested, you can check out my other related articles.

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Nitrile – Wikipedia,
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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 17524-05-9, is researched, Molecular C10H14MoO6, about Novel dioxidomolybdenum complexes containing ONO chelators: Synthesis, physicochemical properties, crystal structures, Hirshfeld surface analysis, DNA binding/cleavage studies, docking, and in vitro cytotoxicity, the main research direction is crystal structure oxomolybdenum ethoxysalicylaldehyde benzoylhydrazone; molybdenum ethoxysalicylaldehyde benzoylhydrazone preparation DNA binding cleavage cytotoxicity.SDS of cas: 17524-05-9.

Dioxidomolybdenum (VI) complexes, [MoO2(ESB)H2O]·DMF (1), [MoO2(ESB)MeOH] (2), and [MoO2(ESB)H2O]·EtOH (3), containing 3-ethoxysalicylaldehyde benzoylhydrazone were synthesized and analyzed using various spectral and anal. techniques such as elemental analyses, IR spectra, UV-visible absorption spectra, x-ray crystallog., and Hirshfeld surface anal. Based on the elemental and spectral anal., six-coordinate geometry was assigned for these complexes wherein the hydrazone ligand binds to the metal center in its dianionic enolate form through ONO donor set. Distorted octahedral geometry of 1 and 2 was evidenced from their crystal structures, which is typical for many cis-dioxido complexes of MoVI. The proligand and the new complexes were examined for their DNA binding, DNA cleavage, and cytotoxic properties. The DNA binding efficiency of the compounds in terms of their binding constants (Kb) of the metal complexes is 1.3727 × 105 M-1, 3.0194 x 104 M-1, and 1.13206 x 104 M-1 for [MoO2(ESB)H2O]·DMF (1), [MoO2(ESB)MeOH] (2), and [MoO2(ESB)H2O]·EtOH (3), resp., indicating that these complexes strongly bind to DNA. To determine the binding interactions of the complexes with DNA and protein (BSA), mol. docking studies were carried out. Gel electrophoresis study reveals the fact that the complexes cleaved supercoiled pUC-18 DNA to nicked form (Form II) in the presence and absence of H2O2. The complexes showed significantly high cytotoxicity against MCF-7 (breast cancer cells).

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Safety of Bis(acetylacetonato)dioxomolybdenum(VI). The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Synthesis of MoO2 and MoO2/Co by laser pyrolysis and its photocatalytic activity. Author is Miao, Baoji; Liu, Shanhu; Zhang, Meng.

Typically, molybdenum dioxide (MoO2), as a promising anode material for LIBs, has triggered much attention owing to its high theor. capacity, low elec. resistivity, high d., affordable cost and it has excellent physico-chem. properties. This report presents a bibliog. study on the synthesis of MoO2 and some results concerning a preliminary study of catalytic MoO2/Co materials synthesis by laser pyrolysis. The objective was to demonstrate the possibility to obtain molybdenum oxide nanoparticles from the laser pyrolysis method. In addition, the photocatalytic activity of the MoO2 nanospheres is investigated.

There is still a lot of research devoted to this compound(SMILES：O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O)Safety of Bis(acetylacetonato)dioxomolybdenum(VI), and with the development of science, more effects of this compound(17524-05-9) can be discovered.

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Nitrile – Wikipedia,
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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 17524-05-9, is researched, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6Journal, Advanced Functional Materials called Synergistically Tuning Electronic Structure of Porous β-Mo2C Spheres by Co Doping and Mo-Vacancies Defect Engineering for Optimizing Hydrogen Evolution Reaction Activity, Author is Ma, Yufei; Chen, Meng; Geng, Hongbo; Dong, Huafeng; Wu, Ping; Li, Xiumin; Guan, Guoqing; Wang, Tiejun, the main research direction is porous molybdenum carbide sphere cobalt doping molybdenum vacancy hydrogen.Related Products of 17524-05-9.

The development of novel non-noble electrocatalysts with controlled structure and surface composition is critical for efficient electrochem. hydrogen evolution reaction (HER). Herein, the rational design of porous molybdenum carbide (β-Mo2C) spheres with different surface engineered structures (Co doping, Mo vacancies generation, and coexistence of Co doping and Mo vacancies) is performed to enhance the HER performance over the β-Mo2C-based catalyst surface. D. functional theory calculations and exptl. results reveal that the synergistic effect of Co doping with Mo vacancies increases the electron d. around the Fermi-level and modulates the d band center of β-Mo2C so that the strength of the Mo-H bond is reasonably optimized, thus leading to an enhanced HER kinetics. As expected, the optimized Co50-Mo2C-12 with porous structure displays a low overpotential (η10 = 125 mV), low-onset overpotential (ηonset = 27 mV), and high exchange c.d. (j0 = 0.178 mA cm-2). Furthermore, this strategy is also successfully extended to develop other effective metal (e.g., Fe and Ni) doped β-Mo2C electrocatalyst, indicating that it is a universal strategy for the rational design of highly efficient metal carbide-based HER catalysts and beyond.

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Wu, Deyong; Han, Li published the article 《Solvothermal synthesis and characterization of visible-light-active MoO3/MoS2 heterostructure》. Keywords: molybdenum oxide sulfide heterostructure photocatalytic activity.They researched the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9 ).Application In Synthesis of Bis(acetylacetonato)dioxomolybdenum(VI). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:17524-05-9) here.

MoO3/MoS2 microspheres were successfully synthesized via one-step solvothermal method. The crystal structure, morphol., and composition of MoO3/MoS2 microspheres were characterized by SEM (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and XPS. And MoO3/MoS2 microspheres exhibited excellent photocatalytic performance in the degradation of methyl orange under visible light irradiation The photocatalytic degradation rate of MoO3/MoS2 microsphere is 18.5 and 2.5 times of pure MoO3 and MoS2, resp. The enhanced photocatalytic activity of MoO3/MoS2 should be attributed to the formation of heterojunctions between MoO3 and MoS2 nanosheets, resulting in the effective separation and utilization of the photo-generated charge carries.

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Nitrile – Wikipedia,
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HPLC of Formula: 17524-05-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Mononuclear and binuclear dioxidomolybdenum(VI) complexes of ONO appended aroylhydrazone: Crystal structures, interaction energy calculation and cytotoxicity. Author is Kuriakose, Daly; Kurup, M. R. Prathapachandra.

Mono- and binuclear cis-MoO2 complexes (1-3) [MoO2(ISF)D] (D = H2O 1, DMSO 2 and 4,4′-bipyridine 3; ISF = 3,5-diiodosalicyaldehyde-2-furoichydrazone) were synthesized and fully characterized by different physicochem. methods. The mol. structures were confirmed unambiguously by single crystal x-ray diffraction studies. The octahedral geometry around the Mo(VI) central atom is satisfied by O, N, O donor atoms of dideprotonated dianionic hydrazone moiety, two oxido oxygens and O/N atoms of the coordinated solvent mols. The asym. unit of complexes 1 and 2 contains one mol. whereas complex 3 contains only half of the mol. The 4,4′-bipyridine mol. acts as a linker that links the two asym. MoO2D moieties to form the binuclear dioxidomolybdenum(VI) in complex 3 with Mo···Mo nonbonding distance of 12.01(10) Å. The relevance of H bonding and nonbonding interactions in the construction of supramol. architectures were studied. The upshots of single crystal studies were reproduced with the aid Hirshfeld surface studies. The pre-eminence of dispersion energy component over other components was established by interaction energy calculations and the energy framework anal. The average interaction energy values for complexes 2 and 3 are -282.3 and -228.3 kJ mol-1, resp. Also the in vitro cytotoxicity of all the synthesized compounds was evaluated against lymphoma ascites cell line.

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